Chapter 19

Arihant Objective Approach to Organic Chemistry for IIT JEE and NEET all Medical Entrances Part 4 · 140 exercises

Problem 1

Which of the following statements about enzymes are true? |CBSE 1995] (i) Enzymes lack in nucleophilic groups (ii) Pepsin is proteolytic enryme (iii) Enzymes catalyse chemical reactions by lowering the activation energy (iv) Enzymes are highly specific both in binding chiral substrates and in catalysing their reactions (a) (i) and (ii) (b) (i) and (ii) (c) (i) and (iv) (d) (ii), (iii) and (iv)

5 step solution

Problem 2

The secondary structure of a protein refers to: ICBSE 1995] (a) mainly denatured proteins and structures of prosthetic groups (b) linear sequence of amino acid residues in the polypeptide chain (c) regular folding patterns of continudus portions of the polypeptide chain. (d) three-dimensional structure, specially the bond between amino acid residues that are far apart from each other in polypeptide chain

4 step solution

Problem 3

The function of enzymes in the living system is tos |CBSE 1996] (a) transport oxygen (b) provide immunity (c) catalyse biochemical reactions (d) provide energy

3 step solution

Problem 4

In DNA the complementary bases are : (a) adenine and thymine, guanine and cytosine (b) uracil and adenine, cytosine and guanine (c) adenine and guanine thymine and cytosine (d) adenine and thymine, guanine and uracil

4 step solution

Problem 5

Which of the following is the sweetest sugar? (a) Sucrose (b) Glucose (c) Fructose (d) Maltose

3 step solution

Problem 6

The hormone which controls the processes hike burning of fats, proteins and carbohydrates to liberate energy in the body is : |CBSE 2000\(]\) (a) cortisone (b) thyroxine (c) adrenalin (d) insulin

4 step solution

Problem 7

Glucose molecule reacts with ' \(X\) number of molecules of phenylhydrazine to yield osazone. The value of ' \(X\) is: [CBSE 2000] (a) four (b) one (c) two (d) three

4 step solution

Problem 8

\(\alpha-\mathrm{D}(+)-\) glucose and \(\beta-\mathrm{D}(+)-\) glucose are : [CBSE 2000] (a) anomers (b) epimers (c) enantiomers (d) geometrical isomers

5 step solution

Problem 9

Which of the following is incorrect? ICBSE (a) \(\mathrm{FeCl}_{3}\) is used in detection of phenol (b) Fehling solution is used in detection of glucose (c) Tollen reagent is used in detection of unsaturation (d) \(\mathrm{NaHSO}_{3}\) is used in detection of carbonyl compound

4 step solution

Problem 10

Which one of the following gives positive Fehling's solution test? |CBSE 2001] (a) Sucrose (b) Glucose (c) Fats (d) Protein

3 step solution

Problem 11

Which of the following is correct? (a) Cycloheptane is an aromatic compound (b) Diastase is an enzyme (c) Acetophenone is an ether (d) All of the above

4 step solution

Problem 12

Which is correct statement? |CBSE 2001] (a) Starch is polymer of \(\alpha\)-glucose (b) Amylose is a component of cellulose (c) Proteins are composed of only one type of amino acid (d) In cyclic structure of fructose, there are four carbons and one oxygen atom

4 step solution

Problem 13

Which statement is incorrect about peptide |CBSE 2001| (a) C-N bond length in proteins is longer than usual bond length of \(\mathrm{C}-\mathrm{N}\) bond (b) Spectroscopic analysis show planar structure of - group (c) \(\mathrm{C}-\mathrm{N}\) bond length in proteins is smaller than usual bond length of \(\mathrm{C}-\mathrm{N}\) bond (d) None of above

4 step solution

Problem 14

Enzymes are made up of : (a) edible proteins (b) proteins with specific structure (c) nitrogen containing carbohydrates (d) carbohydrates

3 step solution

Problem 15

Glycolysis is: (a) oxidation of glucose to pyruvate (b) conversion of glucose to haeme (c) oxidation of glucose to glutamate (d) conversion of pyruvate to citrate

4 step solution

Problem 16

Phospholipids are esters of glycerol with: \(\quad\) [CBSE 2003] (a) one carboxylic acid residue and two phosphate groups (b) three phosphate groups (c) three carboxylic acid residues (d) two carboxylic acid residues and one phosphate group

4 step solution

Problem 18

The enzyme which hydrolyses triglycerides to fatty acids and glycerol is called: |CBSE.2004| (a) maltase (b) lipase (c) zymase (d) pepsin

3 step solution

Problem 19

The correct statement in respect of protein haemoglobin is that it : |CBSE 2004] (a) functions as a catalyst for biological reactions (b) maintains blood sugar level (c) act as an oxygen carrier in the blood (d) forms antibodies and offers resistance to diseases

4 step solution

Problem 20

The helical structure of protein is stabilised by : |CBSE.2004| (a) dipeptide bonds (b) hydrogen bonds (c) ether bonds (d) peptide bonds

5 step solution

Problem 21

A sequence of how many nucleotides in messenger RNA makes a codon for an amino acid? |CBSE 2004] (a) Three (b) Four (c) One (d) Two

4 step solution

Problem 22

The hormone that helps in the conversion of glucose to glycogen is : [CBSE 2004] (a) cortisone (b) bile acids (c) adrenalin (d) insulin

2 step solution

Problem 23

Which functional group participates in disulphide bond formation in proteins? |CBSE 2005] (a) Thiolacetone (b) Thiol (b) Thioether (d) Thioester

3 step solution

Problem 24

\(\alpha\)-D-glucose and \(\beta-D\)-glucose have a specific rotation of \(+112^{\circ}\) and \(+19^{\circ}\) respectively. In aqueous solution the rotation becomes \(+52^{\circ} .\) This is known as: [AFMC 1996] (a) racemisation (b) mutarotation (c) inversion (d) enolisation

4 step solution

Problem 25

The type of vitamins we require daily are: (a) water soluble (b) alcohol soluble (c) fat soluble (d) all of these

4 step solution

Problem 26

The hydrolysis of sugar to glucose and fructose is catalysed by: [AFMC 1998] (a) zymase (b) invertase (c) diastase (d) maltase

7 step solution

Problem 27

Insulin is secreted by: (a) stomach (b) intestine (c) pancreas (d) brain

4 step solution

Problem 28

Glucose \(+\) Tollen's reagent \(\rightarrow\) silver mirror. The above process shows: (a) presence of - COOH group (b) presence of keto group (c) presence of -CHO group (d) presence of \(-\mathrm{CONH}_{2}\) group

4 step solution

Problem 29

Sucrose on treatment with \(\mathrm{HCl}\) produces: (a) glucose (b) fructose (c) both (a) and (b) (d) laevulinic acid

4 step solution

Problem 30

Enzymes are: \(\quad\) [AFMC 2001] (a) moulds (b) inorganic compound (c) proteins (d) micro-organism

5 step solution

Problem 31

Soaps are classified as: (a) carbohydrates (b) salts of fatty acids (c) ethers (d) alcohols

3 step solution

Problem 32

The type of linkage present in protein molecule is: (a) ether linkage (b) peptide linkage (c) stycosidic linkage (d) ester linkage

4 step solution

Problem 33

The base not present in DNA is: (a) uracil (b) guanine (c) adenine (d) cytosine

2 step solution

Problem 34

The group present in wax is: (a) acid group (b) ester group (c) alcohol group (d) ether group

5 step solution

Problem 35

The sugar present in milk is : (a) glucosee (b) lactose (c) maltose (d) sucrose

4 step solution

Problem 36

Monosaccharides are defined as: (a) aldehydes (b) ketones (c) starch (d) non-hydrolysing sugars

6 step solution

Problem 37

The water soluble vitamin is: (a) vitamin B (b) vitamin \(\mathrm{A}\) (c) vitamin \(\mathrm{K}\) (d) vitamin \(\mathrm{E}\)

4 step solution

Problem 38

An organic compound responds to Molisch test. It gives a blue colour with iodine. The compound is : (a) glucose (b) fructose (c) starch (d) tartaric acid

3 step solution

Problem 39

\alpha-D-glucose and \(\beta\)-D-glucose differ from each other due to \mathrm{\\{} ~ d i f f e r e n c e ~ i n ~ c a r b o n ~ a t o m ~ w i t h ~ r e s p e c t ~ t o ~ i t s ~ : ~ (a) structure (b) conformation (c) configuration (d) none of these

4 step solution

Problem 40

The deficiency of iodine in diet causes : (a) rickets (b) nightblindness (c) beri-beri (d) goitre

4 step solution

Problem 41

Chemically ascorbic acid is: (a) vitamin \(\mathrm{B}\) (b) vitamin \(\mathrm{C}\) (c) vitamin \(\mathrm{E}\) (d) vitamin \(\mathrm{B}_{6}\)

3 step solution

Problem 43

Starch is converted into maltose by : (a) invertase (b) amylase (c) diastase (d) zymase

4 step solution

Problem 44

The general molecular formula for disaccharide is : (a) \(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\) (b) \(\mathrm{C}_{10} \mathrm{H}_{20} \mathrm{O}_{10^{+}}\) (c) \(\mathrm{C}_{12} \mathrm{H}_{20} \mathrm{O}_{10}\) (d) \(\mathrm{C}_{12} \mathrm{H}_{2} \mathrm{O}_{10}\)

4 step solution

Problem 45

Deficiency of vitamin-D causes: (a) night blindness (b) rickets (c) scurvy (d) loss of appetite

3 step solution

Problem 46

Sucrose on treatment with conc. HCl produces: (a) glucose (b) fructose (c) both (a) and (b) (d) laevulinic acid

4 step solution

Problem 47

Enzymes having two sites are: \(\quad\) IAIIMS 2002] (a) conjugate enzyme (b) apoenzyme (c) holoenzyme (d) allosteric enzyme

4 step solution

Problem 48

Among the following, the achiral amino acid is: (a) 2 -ethylalanine (b) 2-methylglycine (c) 2-hydroxymethyl serine (d) tryptophen

5 step solution

Problem 49

The nucleic acid base having two possible binding sites is: [AIIMS 2004] (a) thymine (b) cytosine (c) guanine (d) all of these

5 step solution

Problem 50

Which of the following statements is true for protein synthesis (translation)? |AIIMS 2005] (a) Amino acids are directly recognised by m-RNA (b) The third base of the codon is less specific (c) Only one codon codes for an amino acid (d) Every \(t\)-RNA molecule has more than one amino acid attachment

6 step solution

Problem 51

Conversion of starch into maltose takes place by the enzyme: |BHU 1999] (a) invertase (b) maltase (c) diastase (d) zymase

4 step solution

Problem 52

Which one of the following is a conjugated protein? (a) Phosphoprotein (b) Glycoprotein (c) Chromoprotein (d) All of these

5 step solution

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