Carbohydrates

An Introduction to General, Organic, and Biological Chemistry ยท 84 exercises

Q. 13.68

What are the differences in the Haworth structures of α-D-glucose and β-D-glucose? (13.4)

2 step solution

Q. 13.1

What reactants are needed for photosynthesis and respiration?

3 step solution

Q. 13.2

What is the relationship between photosynthesis and respiration?

3 step solution

Q. 13.3

What is a monosaccharide? A disaccharide?

3 step solution

Q. 13.4

What is a polysaccharide?

3 step solution

Q. 13.5

What functional groups are found in all monosaccharides?

3 step solution

Q. 13.6

What is the difference between an aldose and a ketose?

3 step solution

Q. 13.7

What are the functional groups and number of carbons in a ketopentose?

3 step solution

Q. 13.8

What are the functional groups and number of carbons in an aldohexose?

2 step solution

Q. 13.9


Classify each of the following monosaccharides as an aldopentose, ketopentose, aldohexose, or ketohexose:

a. Psicose is present in low amounts in foods. 

b. Lyxose is a component of bacterial glycolipids.

                         

5 step solution

Q. 13.10





Classify each of the following monosaccharides as an aldopentose, ketopentose, aldohexose, or ketohexose:

a. A solution of xylose is given to test its absorption by the intestines. 

b. Tagatose, found in fruit, is similar in sweetness to sugar. 

                                 

5 step solution

Q. 13.27

An infant with galactosemia can utilize D-glucose in milk but not D-galactose. How does the Fischer projection of D-galactose differ from that of D-glucose?

3 step solution

Q. 13.16

Indicate whether each pair of Fischer projections represents enantiomers or identical structures.

8 step solution

Q. 13.11

Identify each of the following structures as chiral or achiral. If chiral, indicate the chiral carbon.

9 step solution

Q. 13.12

Identify each of the following structures as chiral or achiral. If chiral, indicate the chiral carbon.

9 step solution

Q. 13.13

Draw the Fischer Projection for each of the following wedge-dash structures:

7 step solution

Q. 13.14

Draw the Fischer Projection for each of the following wedge-dash structures:

7 step solution

Q. 13.15

Indicate whether each pair of Fisher projections represents enantiomers or identical structures.

9 step solution

Q. 13.19


Identify the chiral carbon in each of the following compounds: 

4 step solution

Q. 13.20

4 step solution

Q. 13.17

Identify each of the following as D or L:

6 step solution

Q. 13.18

Identify each of the following as D or L:

6 step solution

Q.13.23

Draw the Fischer projection for the other enantiomer of a to d in problem 13.21.

8 step solution

Q. 13.21


Identify each of the following as the D or L enantiomer:



5 step solution

Q. 13.22



Identify each of the following as the D or L enantiomer:





5 step solution

Q. 13.23

Draw the Fischer projection for the other enantiomer of a to d in problem 13.21.

6 step solution

Q. 13. 26

Draw the Fischer projections for D-fructose and L-fructose.

3 step solution

Q. 13.26

Draw the Fischer projections for D-fructose and L-fructose.

2 step solution

Q. 13.24



Draw the Fischer projection for the other enantiomer of a to d in problem 13.22.

                         


                       

8 step solution

Q. 13.28

D-Fructose is the sweetest monosaccharide. How does the Fischer projection of D-fructose differ from that of D-glucose?

3 step solution

Q. 13.30

Identify a monosaccharide that fits each of the following descriptions:

a. found in high blood levels in diabetes

b. is also called fruit sugar

4 step solution

Q. 13.29

Identify the monosaccharide that fits each of the following descriptions;

a. is also called blood sugar

b. is not metabolizod in a condition known as galactoscmia

4 step solution

Q. 13.25

Draw the Fischer projections for D-glucose and L-glucose.

3 step solution

Q. 13.21

Identify each of the following as the D or L enantiomer:

a.                      b.

c.                       d.

8 step solution

Q. 13. 23 Draw the fischer projection of a to d of the following diagram






8 step solution

Q. 13.22

Identify each of the following as D or L enantiomer.

8 step solution

Q. 13.31

What are the kind and number of atoms in the ring portion of the Haworth structure of glucose?

3 step solution

Q. 13.32

What are the kind and number of atoms in the ring portion of the Haworth structure of fructose?

3 step solution

Q. 13.33

Draw the Haworth structures for α-Glucose and β-Glucose.

3 step solution

Q. 13.34

Draw the Haworth structures for α - and β-d fructose.

3 step solution

Q. 13.35

ldentify each of the following as the αor β isomer.


4 step solution

Q. 13.36

Identify each of the following as the α or β isomer:


4 step solution

Q. 13.35

Identify each of the following as the α or β isomer :


4 step solution

Q. 13.38

Draw the Fischer projection for the oxidation and the reduction products of D-mannose. What are the names of the sugar acid and the sugar alcohol produced?



4 step solution

Q. 13.37


Draw the fischer projection for the oxidation and the reduction products of D-xylose. what are the names of sugar acid and the sugar alcohol produced?



2 step solution

Q. 13.39

Draw the Fischer projection for the oxidation and the reduction products of D-arabinose. What are the names of the sugar acid and the sugar alcohol produced?


5 step solution

Q. 13.40


Draw the Fischer projection for the oxidation and the reduction products of D-ribose. What are the names of the sugar acid and the sugar alcohol produced?




5 step solution

Q. 13.44

Indicate whether each disaccharide in the following figure is a reducing sugar or not.

a.

 

b.



5 step solution

Q. 13.45

Identify the disaccharide that fits each of the following descriptions:

a. ordinary table sugar

b. found in milk and milk products

c. also called malt sugar

d. hydrolysis gives galactose and glucose

8 step solution

Q. 13.46

Identify the disaccharide that fits each of the following descriptions:

a. not a reducing sugar

b. composed of two glucose units

c. also called milk sugar

d. hydrolysis gives glucose and fructose

6 step solution

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