Q. 13.21

Question

Identify each of the following as the D or L enantiomer:

a.                      b.

c.                       d.

Step-by-Step Solution

Verified
Answer

a. The threose is D enantiomer. 

b. The xylulose is D enantiomer. 

c. The mannose is L enantiomer. 

d. The allose is D enantiomer.  

1Part (a) Step 1: Given Information

We need to identify threose is D or L enantiomer.


 

2Part (a) Step 2: Explanation

In a natural molecule, if the -OH bunch is connected to the base chiral focus and it focuses towards the right then the compound is a D-enantiomer.

In the given construction of threose, the - OH bunch is connected to the base chiral focus and it focuses towards the right. Consequently, it's a D-enantiomer.

3Part (b) Step 1: Given Information

We need to identify whether xylulose is D or L enantiomer.

4Part (b) Step 2: Explanation

In a natural molecule, if the - OH bunch is connected to the base chiral focus and it focuses towards the right then the compound is a D-enantiomer.

In the given design of xylulose, the -OH bunch is appended to the base chiral focus and it focuses towards the right. Hence, it's a D-enantiomer.

5Part (c) Step 1: Given Information

We need to identify whether mannose is D or L enantiomer.

 

6Part (c) Step 2: Explanation

In a natural molecule, if - OH bunch is appended to the base chiral focus and it focuses towards the left then the compound is an L-enantiomer.

In the given construction of Mannose, the -OH bunch is connected to the base chiral focus and it focuses towards the left. In this manner, it's an L-enantiomer.

7Part (d) Step 1: Given Information

We need to identify allose is D or L enantiomer.


 


8Part (d) Step 2: Explanation

In a natural molecule, if the - OH bunch is joined to the base chiral focus and it focuses towards the right then the compound is a D-enantiomer.

In the given construction of allose, the -OH bunch is joined to the base chiral focus and it focuses towards the right. Thusly, it's a D-enantiomer.