Chapter 21

A Complete Resource Book in Chemistry for JEE Main · 124 exercises

Problem 56

Two radioactive elements \(\mathrm{A}\) and \(\mathrm{B}\) have decay constant \(\lambda\) and \(10 \lambda\) respectively. If the decay begins with the same number of atoms of the \(\mathrm{n}\), the ratio of atoms of \(\mathrm{A}\) to those of \(\mathrm{B}\) after time \(1 / 9 \lambda\) will be (a) \(\mathrm{e}^{-3}\) (b) \(\mathrm{e}^{2}\) (c) \(\mathrm{e}\) (d) \(\mathrm{e}^{-1}\)

5 step solution

Problem 58

During a K-electron capture (a) X-rays are emitted (b) neutrous are emitted (c) \(\alpha\) particles are emitted (d) \(\gamma\) rays are emitted

4 step solution

Problem 60

\({ }_{7} \mathrm{~N}^{13}\) changes to \({ }_{6} \mathrm{C}^{13}\) by the emission of (a) proton (b) electron (c) neutron (d) positron

3 step solution

Problem 61

The half-life of a radioactive isotope is 3 hours. If the initial mass of the isotope was \(300 \mathrm{~g}\), the mass which remained undecayed in 18 hours would be (a) \(4.68 \mathrm{~g}\) (b) \(2.34 \mathrm{~g}\) (c) \(1.17 \mathrm{~g}\) (d) \(9.36 \mathrm{~g}\)

5 step solution

Problem 62

If a \(\mathrm{X}^{\mathrm{b}}\) species emits firstly a positron, then \(2 \alpha\) and \(2 \beta\) particles and in last \(1 \alpha\) particle is also emitted and finally converts to \(\mathrm{Y}^{\mathrm{d}}\) species, so the correct relation is (a) \(\mathrm{c}=\mathrm{a}-5, \mathrm{~d}=\mathrm{b}-12\) (b) \(\mathrm{c}=\mathrm{a}-5, \mathrm{~d}=\mathrm{b}-10\) (c) \(\mathrm{c}=\mathrm{a}-6, \mathrm{~d}=\mathrm{b}-0\) (d) \(\mathrm{c}=\mathrm{a}-4, \mathrm{~d}=\mathrm{b}-12\)

6 step solution

Problem 63

A human body required \(0.01 \mu\) activity of radioactive substance after 24 hours. Half-life of radioactive substane is 6 hours. Then injection of maximum activity of a radioactive suhstance that can he injected is (a) \(0.08\) (b) \(0.04\) (c) \(0.16\) (d) \(0.32\)

5 step solution

Problem 64

\({ }_{2} \mathrm{U}^{235}\) nucleus absorbs a neutron and disintegrates into \({ }_{54} \mathrm{Xe}^{139},{ }_{38} \mathrm{Sr}^{94}\) and \(\mathrm{x}\). What will be the product \(\mathrm{x} ?\) (a) 3 neturons (b) 2 neturons (c) \(\alpha\) particle (d) \(\beta\) particle

5 step solution

Problem 65

The radioactive isotope \({ }^{60} \mathrm{Co}_{27}\) which is used in the treatment of cancer can be made by (n, p) reaction. For this reaction, the target nucleus is (a) \({ }_{28} \mathrm{Ni}^{59}\) (b) \({ }_{27} \mathrm{Co}^{59}\) (c) \({ }_{28} \mathrm{Ni}^{60}\) (d) \({ }_{27} \mathrm{Co}^{60}\)

3 step solution

Problem 66

Energy equivalent of \(0.001 \mathrm{mg}\) is (a) \(9 \times 10^{7} \mathrm{ergs}\) (b) \(9 \times 10^{9}\) ergs (c) \(9 \times 10^{7} \mathrm{~J}\) (d) \(9 \times 10^{5} \mathrm{~J}\)

4 step solution

Problem 67

A radioactive substance having a half-life of 3 days was received in 12 days. It was found that there was only \(3 \mathrm{~g}\) of the isotope in the container. The initial weight of the isotope when packed was (a) \(12 \mathrm{~g}\) (b) \(24 \mathrm{~g}\) (c) \(48 \mathrm{~g}\) (d) \(96 \mathrm{~g}\)

4 step solution

Problem 68

The mass of helium atom of mass number 4 is \(4.0026\) amu, while that of neutron and proton is \(1.0087\) and \(1.0078\) respectively in the same scale. Hence, the nuclear binding per nucleon in the helium atom is (a) \(7.18 \mathrm{MeV}\) (b) \(6.18 \mathrm{MeV}\) (c) \(8.18 \mathrm{MeV}\) (d) \(9.18 \mathrm{MeV}\)

4 step solution

Problem 70

The nucleus resulting from \({ }_{92} \mathrm{U}^{238}\) after successive emission of two \(\alpha\) and four \(\beta\) particle is (a) \({ }_{90} \mathrm{Th}^{230}\) (b) \({ }_{92} \mathrm{U}^{230}\) (c) \({ }_{88} \mathrm{Ra}^{230}\) (d) \({ }_{94} \mathrm{Pu}^{230}\)

5 step solution

Problem 71

Decrease in atomic number is observed during. (a) \(\alpha\) emission (b) \(\beta\) emission (c) positron emission (d) electron capture Select the correct answer. (a) \(1,2,3\) (b) \(2,3,4\) (c) \(1,3,4\) (d) \(1,2,3,4\)

5 step solution

Problem 72

The number of neutrons accompanying the formation of \(_{54} \mathrm{Xe}^{139}\) and \({ }_{38} \mathrm{Sr}^{94}\) from the absorption of slow neutrons by \({ }_{92} \mathrm{U}^{235}\) followed by nuclear fission is (a) 0 (b) 2 (c) 1 (d) 3

4 step solution

Problem 73

\({ }_{92} \mathrm{U}^{2.58}\) emits \(8 \alpha\) particles and \(6 \beta\) particle. The neutron/ proton ratio in the product nucleus is (a) \(60 / 41\) (b) \(62 / 41\) (c) \(61 / 62\) (d) \(61 / 40\)

7 step solution

Problem 74

The disintegration constant of a radioactive isotope whose half-life is 3 hours is (a) \(1.57\) per hour (b) \(1.92\) per hour (c) \(1.04\) per hour (d) \(0.231\) per hour

5 step solution

Problem 75

The half-life of a radioactive element is 40 days. Calculate the average life. (a) \(5.76\) days (b) \(57.6\) days (c) 646 days (d) \(4.56\) days

5 step solution

Problem 78

The half-life of a radioactive nuclide is \(0.693\) minutes. The time (in minutes) required for the disintegration of this nuclide from 10 grams to one gram is ........ (a) 1 (b) \(0.693\) (c) \(6.93\) (d) \(2.303\)

6 step solution

Problem 79

The half-life period of radium is 1580 years. It remains \(1 / 16\) after how many years? (a) 1580 years (b) 3160 years (c) 4740 years (d) 6320 years

6 step solution

Problem 80

The radioisotope, tritium \(\left({ }_{3}^{1} \mathrm{H}\right)\) has a half- life of \(12.3\) years. If the initial amount of tritium is \(32 \mathrm{mg}\), how many milligrams of it would remain after \(49.2\) years? (a) \(4 \mathrm{mg}\) (b) \(8 \mathrm{mg}\) (c) \(1 \mathrm{mg}\) (d) \(2 \mathrm{mg}\)

4 step solution

Problem 81

A radioactive isotope decays at such a rate that after 192 minutes only \(1 / 16\) of the origin amount remains. The half-life of the radioactive isotope is (a) \(12 \mathrm{~min}\) (b) \(24 \mathrm{~min}\) (c) \(32 \mathrm{~min}\) (d) \(48 \mathrm{~min}\)

5 step solution

Problem 82

An artificial radioactive isotope has \(_{7} \mathrm{~N}^{14}\) after two successive \(\beta\) particle emissions. The number of neutrons in the parent nucleus must be (a) 14 (b) 9 (c) 7 (d) 5

5 step solution

Problem 83

A radioactive isotope has a half-life of 8 days. If today \(125 \mathrm{mg}\) is left over, what was its original weight 32 days earlier? (a) \(2 \mathrm{~g}\) (b) \(4 \mathrm{~g}\) (c) \(5 \mathrm{~g}\) (d) \(6 \mathrm{~g}\)

4 step solution

Problem 85

If a substance with half-life of 3 days is taken to another place in 12 days. What is the amount of substance left now? (a) \(1 / 8\) (b) \(1 / 32\) (c) \(1 / 4\) (d) \(1 / 16\)

4 step solution

Problem 86

A sample of \({ }_{19} \mathrm{~K}^{40}\) contains invariably \({ }_{18} \mathrm{Ar}^{40} .\) This is because \({ }_{19} \mathrm{~K}^{40}\) has tendency to undergo (a) \(\alpha\) decay (b) positronium decay (c) \(\beta\) decay (d) \(\gamma\) decay

3 step solution

Problem 87

The radioisotope of hydrogen has a half-life of \(12.33\) y. What is the age of an old bottle of wine, whose \({ }_{1} \mathrm{H}^{3}\) radiation is \(10 \%\) of that present in a new bottle of wine? (a) 41 years (b) \(123.3\) years (c) \(1.233\) years (d) 410 years

5 step solution

Problem 88

Lead is the final product formed by a series of changes in which the rate determining stage is the radioactive decay of uranium-238. This radioactive decay is a first order reaction with a half-life of \(4.5 \times 10^{9}\) years. What would be the age of a rock sample originally lead free, in which the molar proportion of uranium to lead is now \(1: 3\) ? (a) \(1.5 \times 10^{9}\) years (b) \(2.25 \times 10^{9}\) years (c) \(4.5 \times 10^{9}\) years (d) \(9.0 \times 10^{9}\) years

6 step solution

Problem 89

The number of neutrons accompanying the formation of \(_{34} \mathrm{Xe}^{139}\) and \(\mathrm{Sr}^{94}\) from the absorption of slow neutron by \({ }_{92} \mathrm{U}^{235}\) followed by nuclear fission is (a) 0 (b) 2 (c) 1 (d) 3

4 step solution

Problem 90

\({ }_{13} \mathrm{Al}^{27}\) is a stable isotope. \({ }_{13} \mathrm{Al}^{29}\) is expected to disintegrate by (a) \(\alpha\) emission (b) \(\beta\) emission (c) positron emission (d) proton emission

5 step solution

Problem 91

The half-life period of a radioactive element is 140 days. After 560 days, one gram of the element will reduce to (a) \(1 / 2 \mathrm{~g}\) (b) \(1 / 4 \mathrm{~g}\) (c) \(1 / 8 \mathrm{~g}\) (d) \(1 / 16 \mathrm{~g}\)

5 step solution

Problem 92

The radiations from a naturally occurring radioactive substance, as seen after deflection by a magnetic field in one direction, are (a) definitely beta rays (b) either alpha or beta rays (c) both alpha and beta rays (d) definitely alpha rays

4 step solution

Problem 93

The half-life of a radio-isotope is three hours. If the mass of the undecayed isotope at the end of 18 hours is \(3.125 \mathrm{~g}\), what was its mass initially? (a) \(300 \mathrm{~g}\) (b) \(200 \mathrm{~g}\) (c) \(180 \mathrm{~g}\) (d) \(400 \mathrm{~g}\)

4 step solution

Problem 95

If \(5 \mathrm{~g}\) of a radioactive substance has \(\mathrm{t}_{1 / \mathrm{s}}=14 \mathrm{hr}, 10 \mathrm{~g}\) of the same substance will have a \(\mathrm{t}_{1,}\) equal to (a) 14 hours (b) 28 hours (c) 50 hours (d) 70 hours

4 step solution

Problem 98

A radioactive element A decays by the sequence and with half-lives given below: \(\mathrm{A} \frac{\alpha}{30 \min }-\mathrm{B} \frac{2 \beta}{2 \text { days }} \rightarrow \mathrm{C}\) Which one of the following statement is correct? (a) after two hours, less than \(10 \%\) of the initial \(\mathrm{A}\) is left (b) maximum amount of B present at any time is less than \(50 \%\) of the initial amount of \(\mathrm{A}\). (c) stomic number of \(\mathrm{A}\) and \(\mathrm{C}\) are same (d) both (a) and (c) are correct

5 step solution

Problem 99

At radioactive equilibrium, the ratio between the atoms of two radioactive elements \(\mathrm{X}\) and \(\mathrm{Y}\) was found to be \(3.1 \times 10^{9}: 1\) respectively. If \(\mathrm{T}_{50}\) of the element \(\mathrm{X}\) is \(2 \times 10^{10}\) years, then \(\mathrm{T}_{50}\) of the element \(\mathrm{Y}\) is (a) \(6.45\) years (b) \(3.1 \times 10^{6}\) years (c) \(6.2 \times 10^{7}\) years (d) \(21 \times 10^{8}\) years

5 step solution

Problem 100

What weight of \(\mathrm{C}^{14}\) will have radioactivity one curie if \(\lambda\) (disintegration constant) is \(4.4 \times 10^{-12} \mathrm{sec}^{-1}\) ? (a) \(3.7 \times 10^{-6} \mathrm{~kg}\) (b) \(51 \times 10^{-3} \mathrm{~kg}\) (c) \(1.96 \times 10^{-4} \mathrm{~kg}\) (d) \(1.7 \times 10^{-6} \mathrm{~kg}\)

5 step solution

Problem 101

Half-life period of the radioactive element \(X\) is 10 hours. Amount of \(X\) left in the 11 th hour starting with one \(\mathrm{mol} \mathrm{X}\) is (a) \((1 / 2)^{1 / 10}\) (b) \((1 / 2)^{11 / 10}\) (c) \((1 / 2)^{12 / 11}\) (d) \((1 / 2)^{1 / 11}\)

4 step solution

Problem 103

A sample of radioactive substance gave 630 counts per minute and 610 counts per minute at times differing by 1 hour. The decay constant \((\lambda)\) in \(\min ^{-1}\) is given by (a) \(\lambda=\frac{630}{610} \times 60\) (b) \(\mathrm{e}^{60 \mathrm{k}}=\frac{630}{610}\) (c) \(\lambda=\frac{2.303}{60} \log \frac{610}{630}\) (d) \(\lambda=\frac{2.303}{60} \times \frac{630}{610}\)

5 step solution

Problem 104

In one type of mutual annihilation of an electron and a positron, three \(\gamma\)-ray photons are produced. If each photon has an energy of \(0.3407 \mathrm{MeV}\), what is the mass of the positron in amu? ( \(1 \mathrm{amu}=931.5 \mathrm{MeV}\) ) (a) \(7.986 \times 10^{-4}\) (b) \(5.486 \times 10^{-4}\) (c) \(16.86 \times 10^{4}\) (d) \(2.243 \times 10^{-4}\)

5 step solution

Problem 105

Assuming the age of the earth to be \(10^{10}\) years, what fraction of the original amount of \({ }_{92} \mathrm{U}^{238}\) is still in existence on earth \(\left(\mathrm{t}_{1 / 2}\right.\) of \({ }_{92} \mathrm{U}^{238}=4.51 \times 10^{9}\) years \()\) ? (a) \(10 \%\) (b) \(20 \%\) (c) \(30 \%\) (d) \(40 \%\)

5 step solution

Problem 107

In the nuclear reaction: \({ }_{3} \mathrm{Li}^{7}+{ }_{1} \mathrm{H}^{1} \longrightarrow 2{ }_{2} \mathrm{He}^{4}\) the mass loss is nearly \(0.02 \mathrm{amu}\). Hence, the energy released (in units of million \(\mathrm{kcal} / \mathrm{mol}\) ) in the process is approximately (a) 100 (b) 200 (c) 400 (d) 600

6 step solution

Problem 108

Match the following: List-I (Series) 1\. thorium 2\. naptunium 3\. actinium 4\. uranium List-II (Particles emitted) (i) \(8 \alpha, 5 \beta\) (ii) \(8 \alpha, 6 \beta\) (iii) \(6 \alpha, 4 \beta\) (iv) \(7 \alpha, 4 \beta\) The correct matching is: 1 2 3 4 (a) (iii) (i) (iv) (ii) (b) (i) (ii) (iv) (iii) (c) (iii) (i) (ii) (iv) (d) (ii) (i) (iv) (iii)

5 step solution

Problem 109

Match the following: List-I (Reactions) 1\. \({ }_{4} \mathrm{Be}^{9}+{ }_{2} \mathrm{He}^{4} \longrightarrow{ }_{6} \mathrm{C}^{12}+\ldots \ldots\) 2\. \({ }_{6} \mathrm{C}^{12}+\ldots \ldots \longrightarrow{ }_{5} \mathrm{~B}^{10}+{ }_{2} \mathrm{He}^{4}\) 3\. \({ }_{7} \mathrm{~N}^{14}+\ldots \ldots \longrightarrow{ }_{8} \mathrm{O}^{17}+{ }_{1} \mathrm{H}^{1}\) 4\. \({ }_{20} \mathrm{Ca}^{40}+\ldots \ldots \longrightarrow{ }_{19} \mathrm{~K}^{37}+{ }_{2} \mathrm{He}^{4}\) List-II (Particles) (i) \({ }_{2} \mathrm{He}^{4}\) (ii) \({ }_{0} \mathrm{n}^{1}\) (iii) \({ }_{1} \mathrm{D}^{2}\) (iv) \({ }_{1} \mathrm{H}^{1}\) The correct matching is: 1 2 3 4 (a) (ii) (i) (iii) (iv) (b) (iii) (ii) (i) (iv) (c) (i) (ii) (iv) (iii) (d) (ii) (iii) (i) (iv)

5 step solution

Problem 110

\({ }_{90} \mathrm{Th}^{232}\) decays to \({ }_{82} \mathrm{~Pb}^{206} .\) How many \(\alpha\) and \(\beta\) particles are emitted? (a) \(7 \alpha, 6 \beta\) (b) \(6 \alpha, 7 \beta\) (c) \(4 \alpha, 3 \beta\) (d) none of these

5 step solution

Problem 112

During the transformation of \(\mathrm{X}^{\mathrm{b}} \longrightarrow \mathrm{C}^{\mathrm{d}}\) the number of \(\beta\) particles emitted is (a) \(\frac{(b-d)}{4}\) (b) \((c-a)+1 / 2(b-d)\) (c) \((a-c)-1 / 2(b-d)\) (d) \((b-d)+2(c-a)\)

6 step solution

Problem 114

A sample of \(\mathrm{U}^{238}\left(\mathrm{t}_{1 / 2}=4.5 \times 10^{9} \mathrm{yrs}\right)\) ore is found con- taining \(23.8 \mathrm{~g} \mathrm{U}^{238}\) and \(20.6 \mathrm{~g}\) of \(\mathrm{Pb}^{206} .\) Calculate the age of the ore. (a) \(4.9 \times 10^{9}\) year (b) \(9.0 \times 10^{11}\) year (c) \(9.4 \times 10^{9}\) year (d) \(4.5 \times 10^{9}\) year

6 step solution

Problem 115

One of the hazards of nuclear explosion is the generation of \(\mathrm{Sr}^{90}\) and its subsequent incorporation in bones. This nuclide has a half life of \(28.1\) years. Suppose one microgram was absorbed by a new born child, how much \(\mathrm{Sr}^{90}\) will remain in his bones after 20 years? (a) \(61 \mu \mathrm{g}\) (b) \(61 \mathrm{~g}\) (c) \(0.61 \mu \mathrm{g}\) (d) none

6 step solution

Problem 117

Which of the following statement is/are correct? (a) The decay constant is independent of external factors like temperature and pressure (b) Nuclear isomers have same number of protons and neutrons (c) The decay constant is independent of the amount of the substance used (d) The value of decay constant generally decreases with the rise in temperature

6 step solution

Problem 118

Which is/are correctly matched? (a) Positron emission : \(\mathrm{n} / \mathrm{p}\) ration increases (b) \(\mathrm{K}\) - electron capture : \(\mathrm{n} / \mathrm{p}\) decreases (c) \(\beta\) - decay: n/p ration decreases (d) \(\alpha\) - decay: \(\mathrm{n} / \mathrm{p}\) ratio increases

4 step solution

Problem 119

Select the correct statements: (a) In the reaction \({ }_{11} \mathrm{Na}^{23}+\mathrm{Q} \rightarrow{ }_{12} \mathrm{Mg}^{23}+{ }_{0} \mathrm{n}^{1}\), the bombarding particle \(\mathrm{q}\) is deutron (b) In the reaction \({ }_{92} \mathrm{U}^{235}+{ }_{0} \mathrm{n}^{1} \rightarrow 56 \mathrm{Ba}^{140}+2\) \({ }_{0} \mathrm{n}^{1}+\mathrm{p}\), produced \(\mathrm{p}\) is \({ }_{36} \mathrm{Kr}^{94}\) (c) In a fission reaction, a loss in mass occurs releasing a huge amount of energy (d) A huge amount of energy is produced during nuclear fission and nuclear fussion reaction

4 step solution

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