Chapter 21
A Complete Resource Book in Chemistry for JEE Main · 114 exercises
Problem 63
A human body required \(0.01 \mu\) activity of radioactive substance after 24 hours. Half-life of radioactive substane is 6 hours. Then injection of maximum activity of a radioactive substance that can be injected is (a) \(0.08\) (b) \(0.04\) (c) \(0.16\) (d) \(0.32\)
5 step solution
Problem 64
\(\mathrm{U}^{235}\) nucleus absorbs a neutron and disintegrates into 9 \({ }_{54} \mathrm{Xe}^{139},{ }_{38} \mathrm{Sr}^{94}\) and \(\mathrm{x}\). What will be the product \(\mathrm{x}\) ? (a) 3 neturons (b) 2 neturons (c) \(\alpha\) particle (d) \(\beta\) particle
5 step solution
Problem 65
The radioactive isotope \({ }^{60} \mathrm{Co}_{27}\) which is used in the treatment of cancer can be made by \((\mathrm{n}, \mathrm{p})\) reaction. For this reaction, the target nucleus is (a) \({ }_{28} \mathrm{Ni}^{59}\) (b) \({ }_{27} \mathrm{Co}^{59}\) (c) \({ }_{28} \mathrm{Ni}^{60}\) (d) \({ }_{27} \mathrm{Co}^{60}\)
3 step solution
Problem 66
Energy equivalent of \(0.001 \mathrm{mg}\) is (a) \(9 \times 10^{7} \mathrm{ergs}\) (b) \(9 \times 10^{4}\) ergs (c) \(9 \times 10^{7} \mathrm{~J}\) (d) \(9 \times 10^{5} \mathrm{~J}\)
4 step solution
Problem 67
A radioactive substance having a half-life of 3 days was received in 12 days. It was found that there was only \(3 \mathrm{~g}\) of the isotope in the container. The initial weight of the isotope when packed was (a) \(12 \mathrm{~g}\) (b) \(24 \mathrm{~g}\) (c) \(48 \mathrm{~g}\) (d) \(96 \mathrm{~g}\)
5 step solution
Problem 68
The mass of helium atom of mass number 4 is \(4.0026\) amu, while that of neutron and proton is \(1.0087\) and \(1.0078\) respectively in the same scale. Hence, the nuclear binding per nucleon in the helium atom is (a) \(7.18 \mathrm{MeV}\) (b) \(6.18 \mathrm{MeV}\) (c) \(8.18 \mathrm{MeV}\) (d) \(9.18 \mathrm{MeV}\)
5 step solution
Problem 69
In natural radioactive disintegration, U-238 emits one \(\alpha\) and two \(\beta\) and then five \(\alpha\) particle successively. The end product obtained is (a) \({ }_{82} \mathrm{~Pb}^{218}\) (b) \({ }_{82} \mathrm{~Pb}^{214}\) (c) \({ }_{84} \mathrm{~Pb}^{218}\) (d) \({ }_{82} \mathrm{~Pb}^{216}\)
4 step solution
Problem 70
The nucleus resulting from \({ }_{92} \mathrm{U}^{238}\) after successive emission of two \(\alpha\) and four \(\beta\) particle is (a) \(\mathrm{Th}^{230}\) (b) \({ }_{92} \mathrm{U}^{230}\) (c) \({ }_{8 \beta} \mathrm{Ra}^{230}\) (d) \({ }_{94} \mathrm{Pu}^{230}\)
4 step solution
Problem 71
Decrease in atomic number is observed during. (a) \(\alpha\) emission (b) \(\beta\) emission (c) positron emission (d) electron capture Select the correct answer. (a) \(1,2,3\) (b) \(2,3,4\) (c) \(1,3,4\) (d) \(1,2,3,4\)
5 step solution
Problem 72
The number of neutrons accompanying the formation of \({ }_{34} \mathrm{Xe}^{139}\) and \({ }_{33} \mathrm{Sr}^{94}\) from the absorption of slow neutrons by \({ }_{92} \mathrm{U}^{235}\) followed by nuclear fission is (a) 0 (b) 2 (c) 1 (d) 3
4 step solution
Problem 73
\(\mathrm{U}^{238}\) emits \(8 \alpha\) particles and \(6 \beta\) particle. The neutron/ proton ratio in the product nucleus is (a) \(60 / 41\) (b) \(62 / 41\) (c) \(61 / 62\) (d) \(61 / 40\)
6 step solution
Problem 74
The disintegration constant of a radioactive isotope whose half-life is 3 hours is (a) \(1.57\) per hour (b) \(1.92\) per hour (c) \(1.04\) per hour (d) \(0.231\) per hour
5 step solution
Problem 75
The half-life of a radioactive element is 40 days. Calculate the average life. (a) \(5.76\) days (b) \(57.6\) days (c) 646 days (d) \(4.56\) days
5 step solution
Problem 77
One microgram of radioactive sodium \({ }_{11} \mathrm{Na}^{24}\) with a half- life of 15 hours was injected into a living system for a bio assay. How long will it take for the radioactivity to fall to \(25 \%\) of the initial value? (a) 60 hours (b) \(22.5\) hours (c) 375 hours (d) 30 hours
3 step solution
Problem 78
The half-life of a radioactive nuclide is \(0.693\) minutes. The time (in minutes) required for the disintegration of this nuclide from 10 grams to one gram is ........ (a) 1 (b) \(0.693\) (c) \(6.93\) (d) \(2.303\)
6 step solution
Problem 79
The half-life period of radium is 1580 years. It remains \(1 / 16\) after how many years? (a) 1580 years (b) 3160 years (c) 4740 years (d) 6320 years
4 step solution
Problem 80
The half-life period of radium is 1580 years. It remains \(1 / 16\) after how many years? (a) 1580 years (b) 3160 years (c) 4740 years (d) 6320 years
5 step solution
Problem 81
A radioactive isotope decays at such a rate that after 192 minutes only \(1 / 16\) of the origin amount remains. The half-life of the radioactive isotope is (a) \(12 \mathrm{~min}\) (b) \(24 \mathrm{~min}\) (c) \(32 \mathrm{~min}\) (d) \(48 \mathrm{~min}\)
4 step solution
Problem 82
An artificial radioactive isotope has \({ }_{7} \mathrm{~N}^{14}\) after two successive \(\beta\) particle emissions. The number of neutrons in the parent nucleus must be (a) 14 (b) 9 (c) 7 (d) 5
4 step solution
Problem 83
An artificial radioactive isotope has \({ }_{7} \mathrm{~N}^{14}\) after two successive \(\beta\) particle emissions. The number of neutrons in the parent nucleus must be (a) 14 (b) 9 (c) 7 (d) 5
4 step solution
Problem 84
Observe the following statements regarding isotopes I. \(\mathrm{K}^{39}\) and \(\mathrm{Ca}^{40}\) are isotones II. Nuclides having different atomic number \((\mathrm{Z})\) and mass number (a) but same number of neutrons (n) are called isotones. III. \(\mathrm{F}^{19}\) and \(\mathrm{Na}^{23}\) are isotones. The correct answer is (a) only I and II are correct (b) I, II and III are correct (c) only I and III are correct (d) only II and III are correct
5 step solution
Problem 85
If a substance with half-life of 3 days is taken to another place in 12 days. What is the amount of substance left now? (a) \(1 / 8\) (b) \(1 / 32\) (c) \(1 / 4\) (d) \(1 / 16\)
3 step solution
Problem 86
A sample of \({ }_{19} \mathrm{~K}^{40}\) contains invariably \({ }_{18} \mathrm{Ar}^{40} .\) This is because \({ }_{19} \mathrm{~K}^{40}\) has tendency to undergo (a) \(\alpha\) decay (b) positronium decay (c) \(\beta\) decay (d) \(\gamma\) decay
4 step solution
Problem 87
The radioisotope of hydrogen has a half-life of \(12.33\) y. What is the age of an old bottle of wine, whose, \(\mathrm{H}^{3}\) radiation is \(10 \%\) of that present in a new bottle of wine? (a) 41 years (b) \(123.3\) years (c) \(1.233\) years (d) 410 years
5 step solution
Problem 88
Lead is the final product formed by a series of changes in which the rate determining stage is the radioactive decay of uranium-238. This radioactive decay is a first order reaction with a half-life of \(4.5 \times 10^{9}\) years. What would be the age of a rock sample originally lead free, in which the molar proportion of uranium to lead is now \(1: 3 ?\) (a) \(1.5 \times 10^{9}\) years (b) \(2.25 \times 10^{9}\) years (c) \(4.5 \times 10^{9}\) years (d) \(9.0 \times 10^{9}\) years
7 step solution
Problem 89
The number of neutrons accompanying the formation of \(_{54} \mathrm{Xe}^{139}\) and \({ }_{38} \mathrm{Sr}^{24}\) from the absorption of slow neutron by \({ }_{92} \mathrm{U}^{235}\) followed by nuclear fission is (a) 0 (b) 2 (c) 1 (d) 3
5 step solution
Problem 90
\({ }_{13} \mathrm{Al}^{27}\) is a stable isotope. \({ }_{13} \mathrm{Al}^{29}\) is expected to disintegrate by (a) \(\alpha\) emission (b) \(\beta\) emission (c) positron emission (d) proton emission
4 step solution
Problem 91
The half-life period of a radioactive element is 140 days. After 560 days, one gram of the element will reduce to (a) \(1 / 2 \mathrm{~g}\) (b) \(1 / 4 \mathrm{~g}\) (c) \(1 / 8 \mathrm{~g}\) (d) \(1 / 16 \mathrm{~g}\)
4 step solution
Problem 93
The half-life of a radio-isotope is three hours. If the mass of the undecayed isotope at the end of 18 hours is \(3.125 \mathrm{~g}\), what was its mass initially? (a) \(300 \mathrm{~g}\) (b) \(200 \mathrm{~g}\) (c) \(180 \mathrm{~g}\) (d) \(400 \mathrm{~g}\)
6 step solution
Problem 95
If \(5 \mathrm{~g}\) of a radioactive substance has \(\mathrm{t}_{\mathrm{w}}=14 \mathrm{hr}, 10 \mathrm{~g}\) of the same substance will have a \(t_{1 /}\) equal to (a) 14 hours (b) 28 hours (c) 50 hours (d) 70 hours
3 step solution
Problem 99
At radioactive equilibrium, the ratio between the atoms of two radioactive elements \(\mathrm{X}\) and \(\mathrm{Y}\) was found to be \(3.1 \times 10^{9}: 1\) respectively. If \(\mathrm{T}_{50}\) of the element \(\mathrm{X}\) is \(2 \times 10^{10}\) years, then \(\mathrm{T}_{50}\) of the element \(\mathrm{Y}\) is (a) \(6.45\) years (b) \(3.1 \times 10^{6}\) years (c) \(6.2 \times 10^{7}\) years (d) \(21 \times 10^{8}\) years
7 step solution
Problem 100
What weight of \(\mathrm{C}^{14}\) will have radioactivity one curie if \(\lambda\) (disintegration constant) is \(4.4 \times 10^{-12} \mathrm{sec}^{-1}\) ? (a) \(3.7 \times 10^{-6} \mathrm{~kg}\) (b) \(51 \times 10^{-3} \mathrm{~kg}\) (c) \(1.96 \times 10^{-4} \mathrm{~kg}\) (d) \(1.7 \times 10^{-6} \mathrm{~kg}\)
5 step solution
Problem 101
Half-life period of the radioactive element \(X\) is 10 hours. Amount of \(X\) left in the 11 th hour starting with one \(m o l X\) is (a) \((1 / 2)^{1 / 10}\) (b) \((1 / 2)^{11 / 10}\) (c) \((1 / 2)^{12 / 11}\) (d) \((1 / 2)^{1 / 11}\)
5 step solution
Problem 103
A sample of radioactive substance gave 630 counts per minute and 610 counts per minute at times differing by 1 hour. The decay constant \((\lambda)\) in \(\min ^{-1}\) is given by (a) \(\lambda=\frac{630}{610} \times 60\) (b) \(\mathrm{e}^{60 \mathrm{~A}}=\frac{630}{610}\) (c) \(\lambda=\frac{2.303}{60} \log \frac{610}{630}\) (d) \(\lambda=\frac{2.303}{60} \times \frac{630}{610}\)
6 step solution
Problem 104
In one type of mutual annihilation of an electron and a positron, three \gamma-ray photons are produced. If each photon has an energy of \(0.3407 \mathrm{MeV}\), what is the mass of the positron in amu? ( \(1 \mathrm{amu}=931.5 \mathrm{MeV}\) ) (a) \(7.986 \times 10^{4}\) (b) \(5.486 \times 10^{-4}\) (c) \(16.86 \times 10^{-4}\) (d) \(2.243 \times 10^{-4}\)
6 step solution
Problem 105
Assuming the age of the earth to be \(10^{10}\) years, what fraction of the original amount of \({ }_{92} \mathrm{U}^{218}\) is still in existence on earth \(\left(\mathrm{t}_{h}\right.\) of \({ }_{92} \mathrm{U}^{238}=4.51 \times 10^{9}\) years \()\) ? (a) \(10 \%\) (b) \(20 \%\) (c) \(30 \%\) (d) \(40 \%\)
3 step solution
Problem 106
Match the following: List-I List-II 1\. \(\mathrm{P}^{32}\) (i) Location of the tumour in the brain 2\. \(\mathrm{Na}^{24}\) (ii) Location of the blood clots and circulatory disorders 3\. \(\mathrm{Co}^{\infty 0}\) (iii) Radiotherapy 4\. \(\mathrm{I}^{131}\) (iv) Agricultural research The correct matching is: \(\begin{array}{lll}1 & 2 & 3\end{array}\) 4 (a) (iv) (ii) (iii) (i) (b) (iii) (i) (ii) (iv) (c) (iv) (i) (iii) (ii) (d) (ii) (iv) (i) (ii)
3 step solution
Problem 107
In the nuclear reaction: \({ }_{3} \mathrm{Li}^{7}+{ }_{1} \mathrm{H}^{1} \longrightarrow 2{ }_{2} \mathrm{He}^{4}\) the mass loss is nearly \(0.02\) amu. Hence, the energy released (in units of million \(\mathrm{kcal} / \mathrm{mol}\) ) in the process is approximately (a) 100 (b) 200 (c) 400 (d) 600
4 step solution
Problem 109
Match the following: List-I List-II (Reactions) \(\quad\) (Particles) 1\. \({ }_{4} \mathrm{Be}^{9}+{ }_{2} \mathrm{He}^{4} \longrightarrow{ }_{6} \mathrm{C}^{12}+\ldots \ldots\) (i) \({ }_{2} \mathrm{He}^{4}\) 2\. \({ }_{6} \mathrm{C}^{12}+\ldots \ldots \longrightarrow{ }_{5} \mathrm{~B}^{10}+{ }_{2} \mathrm{He}^{4}\) (ii) \(\mathrm{n}^{1}\) \(3 ., \mathrm{N}^{14}+\ldots \ldots \longrightarrow{ }_{8} \mathrm{O}^{17}+{ }_{1} \mathrm{H}^{1}\) (iii) \({ }_{1} \mathrm{D}^{2}\) 4\. \({ }_{20} \mathrm{Ca}^{40}+\ldots \ldots \longrightarrow{ }_{19} \mathrm{~K}^{37}+{ }_{2} \mathrm{He}^{4}\) (iv) \({ }_{1} \mathrm{H}^{\prime}\) The correct matching is: 1 \(\begin{array}{lll}2 & 3 & 4\end{array}\) (a) (ii) (i) (iii) (iv) (b) (iii) (ii) (i) (iv) (c) (i) (ii) (iv) (iii) (d) (ii) (iii) (i) (iv)
5 step solution
Problem 110
\({ }_{90} \mathrm{Th}^{232}\) decays to \({ }_{82} \mathrm{~Pb}^{206} .\) How many \(\alpha\) and \(\beta\) particles are emitted? (a) \(7 \alpha, 6 \beta\) (b) \(6 \alpha, 7 \beta\) (c) \(4 \alpha, 3 \beta\) (d) none of these
5 step solution
Problem 117
Which of the following statement is/are correct? (a) The decay constant is independent of external factors like temperature and pressure (b) Nuclear isomers have same number of protons and neutrons (c) The decay constant is independent of the amount of the substance used (d) The value of decay constant generally decreases with the rise in temperature
4 step solution
Problem 118
Which is/are correctly matched? (a) Positron emission : \(\mathrm{n} / \mathrm{p}\) ration increases (b) \(\mathrm{K}\) - electron capture : \(\mathrm{n} / \mathrm{p}\) decreases (c) \(\beta\) - decay : \(\mathrm{n} / \mathrm{p}\) ration decreases (d) \(\alpha-\) decay : \(\mathrm{n} / \mathrm{p}\) ratio increases
4 step solution
Problem 119
Select the correct statements: (a) In the reaction \({ }_{11} \mathrm{Na}^{23}+\mathrm{Q} \rightarrow{ }_{12} \mathrm{Mg}^{23}+{ }_{0} \mathrm{n}^{1}\), the bombarding particle \(\mathrm{q}\) is deutron (b) In the reaction \({ }_{92} \mathrm{U}^{235}+{ }_{0} \mathrm{n}^{1} \rightarrow 56 \mathrm{Ba}^{140}+2\) \({ }_{0} \mathrm{n}^{\prime}+\mathrm{p}\), produced \(\mathrm{p}\) is \({ }_{36} \mathrm{Kr}^{94}\) (c) In a fission reaction, a loss in mass occurs releasing a huge amount of energy (d) A huge amount of energy is produced during nuclear fission and nuclear fussion reaction
4 step solution
Problem 120
Select the correct statements: (a) In the reaction \({ }_{11} \mathrm{Na}^{23}+\mathrm{Q} \rightarrow{ }_{12} \mathrm{Mg}^{23}+{ }_{0} \mathrm{n}^{1}\), the bombarding particle \(\mathrm{q}\) is deutron (b) In the reaction \({ }_{92} \mathrm{U}^{235}+{ }_{0} \mathrm{n}^{1} \rightarrow 56 \mathrm{Ba}^{140}+2\) \({ }_{0} \mathrm{n}^{\prime}+\mathrm{p}\), produced \(\mathrm{p}\) is \({ }_{36} \mathrm{Kr}^{94}\) (c) In a fission reaction, a loss in mass occurs releasing a huge amount of energy (d) A huge amount of energy is produced during nuclear fission and nuclear fussion reaction
4 step solution
Problem 123
Which relation is/are correct? (a) \(1 \mathrm{Ci}=3.7 \times 10^{10} \mathrm{~Bq}\) (b) \(1 \mathrm{Ci}=2.8 \mathrm{v} 10^{4} \mathrm{Rd}\) (c) \(1 \mathrm{~Bq}=1\) dps. (d) \(1 \mathrm{~Bq}=10^{6} \mathrm{Rd}\)
5 step solution
Problem 124
Which of the following statements is/are incorrect, when the nuclide, \({ }_{19} \mathrm{~K}^{40}\), is subject to \(\mathrm{K}\)-electron capture? (a) \({ }^{40} \mathrm{Ar}\) is produced with emission of \(\beta\)-particle. (b) \({ }^{40} \mathrm{Ar}\) is produced with emission of \(\alpha\)-particles. (c) \({ }^{40} \mathrm{Ar}\) is produced without emission of radiation (d) \({ }^{40} \mathrm{Ar}\) is produced with emission of X-radiation.
5 step solution
Problem 125
An unstable nucleus is characterized by (i) \(\mathrm{n} / \mathrm{p}>1\) (ii) low binding energy (iii) high temperature and pressure (iv) high packing fraction(a) (i), (ii) (b) (i), (ii), (iv) (c) (i), (ii), (iii) (d) (i), (ii), (iii), (iv)
6 step solution
Problem 127
How much time is required for a \(5.75-\mathrm{mg}\) sample of \({ }^{51} \mathrm{Cr}\) to decay to \(1.50 \mathrm{mg}\) if it has a half-life of \(27.8\) days? (a) \(5.39\) days (b) \(2.69\) days (c) \(53.9\) days (d) \(5.49\) days
5 step solution
Problem 128
Potassium \(-40\) decays to argon \(-40\) with a half life of \(1.27 \times 10^{9} \mathrm{yr}\). What is the age of a rock in which the mass ratio of \({ }^{40} \mathrm{Ar}\) to \({ }^{40} \mathrm{~K}\) is \(3.6\) ? (a) \(2.8 \times 10^{10} \mathrm{yr}\) (b) \(1.4 \times 10^{9} \mathrm{yr}\) (c) \(1.4 \times 10^{10} \mathrm{yr}\) (d) \(2.8 \times 10^{9} \mathrm{yr}\)
7 step solution
Problem 129
Which of the following option is correct? (a) In living organisms, circulation of \({ }^{14} \mathrm{C}\) from atmosphere is high so the carbon content is constant in organism. (b) carbon dating can be used to find out the age of earth crust and rocks (c) radioactive absorption due to cosmic radiation is equal to the rate of radioactive decay, hence the carbon content remains constant in living organism (d) carbon dating can not be used to determine concentration of \({ }^{14} \mathrm{C}\) in dead beings. [IIT 2006]
4 step solution