Chapter 15

Which of the following Can beoxidized by \(\mathrm{O}_{3}\) ? (a) KI (b) \(\mathrm{FeSO}_{4}\) (c) \(\mathrm{KMnO}_{4}\) (d) \(\mathrm{K}_{2} \mathrm{MnO}_{4}\)

Which of the following statements regarding hydrogen peroxide is /are incorrect? (a) The two hydroxyl groups in hydrogen peroxide lie in the same plane (b) Aqueous solution of \(\mathrm{H}_{2} \mathrm{O}_{2}\) turns blue litmus red (c) When \(\mathrm{H}_{2} \mathrm{O}_{2}\) behaves as a reducing agent, the \(\mathrm{O}-\mathrm{O}\) bond in its molecules is not broken down (d) Aqueous solution of \(\mathrm{H}_{2} \mathrm{O}_{2}\) is stored in plastic bottles and some urea, phosphoric acid or glycerol is added to that solution

Which of the following statement (s) is /are correct? (a) Ammonia is oxidized to \(\mathrm{NO}_{2}\) by oxygen at \(800^{\circ} \mathrm{C}\) in presence of a catalyst platinum (b) Nitric acid on standing slowly turns yellow. (c) Colloidal sulphur is formed when \(\mathrm{H}_{2} \mathrm{~S}\) gas is passed through nitric acid solution (d) \(\mathrm{N}_{2} \mathrm{O}_{3}\) gas dissolves in water giving a pale blue solution.

Buckminsterfullerene is prepared by (a) Vapourisation carbon by resistive heating (b) Passing an arc discharge between carbon electrodes in a tube containing helium at 100 torr (c) The pulsed laser vapourisation of graphite (d) None of these

The nitrogen oxide(s) that contains(s) \(\mathrm{N}-\mathrm{N}\) bond(s) is are (a) \(\mathrm{N}_{2} \mathrm{O}\) (b) \(\mathrm{N}_{2} \mathrm{O}_{3}\) (c) \(\mathrm{N}_{2} \mathrm{O}_{4}\) (d) \(\mathrm{N}_{2} \mathrm{O}_{5}\)

Which is the most thermodynamically stable allotropic from of phosphorus? (a) White (b) Black (c) Yellow (d) Red

The incorrect statement about structure of white phosphorus is (a) It has four \(\mathrm{P}=\mathrm{P}\) single bonds. (b) It has six P- P single bonds. (c) It has PPP angle of \(60^{\circ}\) (d) It has four lone pairs of electrons.

Match the following Column-I (Manufacturing process) (a) Deacon's process for chlorine (b) Hydrogenation of vegetable oils (c) Ostwald's process for nitric acid (d) Haber's process for ammonia Column-II (Catalyst used)] (p) Finely divided iron with molybdenum as promoter (q) Copper (II) chloride (r) Finely divided nickel powder (s) Platinum gauze

Match the following Column-I (a) 10 volumes (b) 20 volumes (c) 30 volumes (d) \(11.2\) volumes Column-II (p) \(5.358 \mathrm{~N}\) (q) \(3.036 \%(\mathrm{w} / \mathrm{v})\) (r) \(3.4 \mathrm{gm} \mathrm{H}_{2} \mathrm{O}_{2} / 100\) \(\mathrm{ml}\) solution (s) \(1.785 \mathrm{M}\)

Match the following Column-I (a) Peroxide (b) Superoxide (c) Dioxide (d) Suboxide Column-II (p) \(\mathrm{C}_{3} \mathrm{O}_{2}\) (q) \(\mathrm{PbO}_{2}\) (r) \(\mathrm{KO}_{2}\) (s) \(\mathrm{H}_{2} \mathrm{O}_{2}\) \(\mathrm{F}\) (t) \(\mathrm{RbO}_{2}\)

Match the following Column-I (a) \(\mathrm{Sn}+\) conc. \(\mathrm{HNO}_{3}\) (b) \(\mathrm{Sn}+\mathrm{di} . \mathrm{HNO}_{3}\) (c) \(\mathrm{Ag}+\) conc. \(\mathrm{HNO}_{3}\) (d) \(\mathrm{Ag}+\) dil. \(\mathrm{HNO}_{3}\) Column-II (p) NO (q) \(\mathrm{NO}_{2}\) (r) \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) (s) \(\mathrm{Sn}\left(\mathrm{NO}_{3}\right)_{2}\) (t) \(\mathrm{AgNO}_{3}\)

Column-I (a) \(\mathrm{HNO}_{2}\) (aq) \(\longrightarrow\) (b) \(\mathrm{NH}_{4} \mathrm{Cl}\) (aq) \(+\mathrm{NaNO}_{2}\) (aq) \(\longrightarrow\) (c) \(\mathrm{HN}_{3}+\mathrm{Li} \longrightarrow\) (d) \(\mathrm{Mg}+\mathrm{HNO}_{3}\) (cold and dilute) \(\longrightarrow\) Column-II (p) One of the product is a diamagnetic colourless gas. (q) One of the products is a colourless paramagnetic gas. (r) Redox reaction (s) One of the products gives brown ring test.

Among the following, the number of compounds than can react with \(\mathrm{PCl}_{5}\) to give \(\mathrm{POCl}_{3}\) is \(\mathrm{O}_{2}, \mathrm{CO}_{2}, \mathrm{SO}_{2}\), \(\mathrm{H}_{2} \mathrm{O}, \mathrm{H}_{2} \mathrm{SO}_{4}, \mathrm{P}_{4} \mathrm{O}_{10}\)

The total number of diprotic acids among the following is [IIT 2010] \(\mathrm{H}_{3} \mathrm{PO}_{4} \quad \mathrm{H}_{2} \mathrm{SO}_{4} \quad \mathrm{H}_{3} \mathrm{PO}_{3} \quad \mathrm{H}_{2} \mathrm{CO}_{3} \quad \mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{7}\) \(\mathrm{H}_{3} \mathrm{BO}_{3} \quad \mathrm{H}_{3} \mathrm{PO}_{2} \quad \mathrm{H}_{2} \mathrm{CrO}_{4} \quad \mathrm{H}_{2} \mathrm{SO}_{3}\)

Which of the following can act as a propellant for rockets? (a) liquid hydrogen + liquid nitrogen (b) liquid nitrogen + liquid oxygen (c) liquid hydrogen + liquid oxygen (d) liquid oxygen + liquid argon

Which one of the following substances has the highest proton affinity? (a) \(\mathrm{NH}_{3}\) (b) \(\mathrm{H}_{2} \mathrm{O}\) (c) \(\mathrm{PH}_{3}\) (d) \(\mathrm{H}_{2} \mathrm{~S}\)

Which one of the following processes will produce hard water? (a) saturation of water with \(\mathrm{CaCO}_{3}\) (b) addition of \(\mathrm{Na}_{2} \mathrm{SO}_{4}\) to water (c) saturation of water with \(\mathrm{MgCO}_{3}\) (d) saturation of water with \(\mathrm{CaSO}_{4}\)

One mole of magnesium nitride on the reaction with an excess of water gives (a) two moles of ammonia (b) two moles of nitric acid (c) one mole of ammonia (d) one mole of nitric acid

Which one of the following is the correct statement? (a) Boric acid is a protonic acid (b) Beryllium exhibits coordination number of six. (c) Chlorides of both beryllium and aluminium have bridged chloride structures in solid phase. (d) \(\mathrm{B}_{2} \mathrm{H}_{6} \cdot 2 \mathrm{NH}_{3}\) is known as 'inorganic benzene'

In context with the industrial preparation of hydrogen from water gas \(\left(\mathrm{CO}+\mathrm{H}_{2}\right)\), which of the following is the correct statement? (a) \(\mathrm{CO}\) and \(\mathrm{H}_{2}\) are fractionally separated using differences in their densities (b) \(\mathrm{CO}\) is removed by absorption in aqueous \(\mathrm{Cu}_{2} \mathrm{Cl}_{2}\) solution (c) \(\mathrm{H}_{2}\) is removed through occlusion with \(\mathrm{Pd}\) (d) \(\mathrm{CO}\) is oxidized to \(\mathrm{CO}_{2}\) with steam in the pres- ence of a catalyst followed by absorption of \(\mathrm{CO}_{2}\) in alkali.

Among the following substituted silanes the one which will give rise to cross linked silicone polymer on hydrolysis is \([\mathbf{2 0 0 8}]\) (a) \(\mathrm{R}_{4} \mathrm{Si}\) (b) \(\mathrm{RSiCl}_{3}\) (c) \(\mathrm{R}_{2} \mathrm{SiCl}_{2}\) (d) \(\mathrm{R}_{3} \mathrm{SiCl}\)

Very pure hydrogen \((99.9 \%)\) can be made by which of the following proceses? (a) Reaction of methane with steam (b) Reaction of salt like hydrides with water (c) Electrolysis of water (d) Mixing natural hydrocarbons of high molecular weight

Which of the following statement about water is false? (a) Water can act both as an acid and as a base. (b) There is a extensive intramolecular hydrogen bonding in the condensed phase. (c) Ice formed by heavy water sinks in normal water (d) Water in oxidised to \(\mathrm{O}_{2}\) daring photosynthesis.