Problem 53
Question
The cesium isotope \({ }^{137} \mathrm{Cs}\) is present in the fallout from aboveground detonations of nuclear bombs. Because it decays with a slow \((30.2 \mathrm{y})\) half-life into \({ }^{137} \mathrm{Ba},\) releasing considerable energy in the process, it is of environmental concern. The atomic masses of the Cs and \(\mathrm{Ba}\) are 136.9071 and \(136.9058 \mathrm{u},\) respectively; calculate the total energy released in such a decay.
Step-by-Step Solution
Verified Answer
The total energy released is 1.213 MeV.
1Step 1: Determine the Mass Defect
The mass defect, \( \Delta m \), is the difference in mass between the initial isotope \( \left( {}^{137} \mathrm{Cs} \right) \) and the final isotope \( \left( {}^{137} \mathrm{Ba} \right) \). It can be calculated as \( \Delta m = m_\text{Cs} - m_\text{Ba} \), where \( m_\text{Cs} = 136.9071 \, \text{u} \) and \( m_\text{Ba} = 136.9058 \, \text{u} \). Substituting these values gives \( \Delta m = 136.9071 - 136.9058 = 0.0013 \, \text{u} \).
2Step 2: Convert Mass Defect to Energy
Using the mass-energy equivalence principle, \( E = \Delta m c^2 \), where \( c \) is the speed of light \( 3 \times 10^8 \text{ m/s} \). First, convert \( \Delta m \) from atomic mass units to kilograms using \( 1 \, \text{u} = 1.660539 \times 10^{-27} \text{ kg} \). Thus, \( \Delta m = 0.0013 \, \text{u} \times 1.660539 \times 10^{-27} \text{ kg/u} = 2.1587 \times 10^{-30} \text{ kg} \). Then, \( E = 2.1587 \times 10^{-30} \text{ kg} \times (3 \times 10^8 \text{ m/s})^2 \).
3Step 3: Calculate the Energy Released
Calculate the energy: \[ E = 2.1587 \times 10^{-30} \text{ kg} \times 9 \times 10^{16} \text{ m}^2/\text{s}^2 = 1.94283 \times 10^{-13} \text{ Joules} \]. This is the total energy released during the decay of one atom of \( {}^{137}\text{Cs} \) into \( {}^{137}\text{Ba} \).
4Step 4: Convert Energy to MeV
To convert the energy from Joules to mega-electronvolts (MeV), use the conversion factor \( 1 \, \text{J} = 6.242 \times 10^{12} \, \text{MeV} \). Thus, the energy is: \[ 1.94283 \times 10^{-13} \, \text{J} \times 6.242 \times 10^{12} \, \text{MeV/J} = 1.213 \, \text{MeV} \]. This is the energy released in MeV.
Key Concepts
Mass DefectEnergy ConversionHalf-LifeCesium-137 Decay
Mass Defect
In nuclear physics, the concept of mass defect is crucial to understanding energy release during nuclear decay. Mass defect (\( \Delta m \)) refers to the small difference in mass between the original nucleus and the sum of the masses of its decay products. When cesium-137 (\( {}^{137} \mathrm{Cs} \)) decays into barium-137 (\( {}^{137} \mathrm{Ba} \)), there is a tiny mass difference that accounts for the energy released in the process. In this exercise, the mass defect calculated is\[\Delta m = m_{\text{Cs}} - m_{\text{Ba}} = 0.0013 \ \text{u},\]where atomic mass units (u) provide a useful scale for the subatomic world.
Energy Conversion
Mass-energy equivalence, famously summarized by Einstein's equation \( E = mc^2 \), allows us to understand how a seemingly negligible mass defect can lead to significant energy release. Converting the mass defect from atomic mass units (u) to kilograms is the first step. We use:
- \( 1 \ \text{u} \approx 1.660539 \times 10^{-27} \ \text{kg} \).
Half-Life
The concept of half-life is central when discussing nuclear decay. It is defined as the time required for half of a sample of radioactive atoms to decay. For cesium-137, the half-life is notably lengthy at 30.2 years. This means that if you start with a certain amount of cesium-137, half of it would decay into barium-137 over 30.2 years.
The significance of this for environmental and health concerns is substantial:
- Long half-life implies prolonged environmental presence.
- Radioactive contaminants remain active sources of radiation for extended periods.
Cesium-137 Decay
Cesium-137 is a well-known fission product of nuclear reactions and bomb detonations, and its decay is an important study in nuclear chemistry. Decay of cesium-137 is primarily beta decay, leading to the formation of barium-137. This transition is represented as:
- \( {}^{137}\text{Cs} \rightarrow {}^{137}\text{Ba} + \beta^- \).
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