Problem 50
Question
Large radionuclides emit an alpha particle rather than other combinations of nucleons because the alpha particle has such a stable, tightly bound structure. To confirm this statement, calculate the disintegration energies for these hypothetical decay processes and discuss the meaning of your findings: (a) \({ }^{235} \mathrm{U} \rightarrow{ }^{232} \mathrm{Th}+{ }^{3} \mathrm{He},\) (b) \({ }^{235} \mathrm{U} \rightarrow{ }^{231} \mathrm{Th}+{ }^{4} \mathrm{He}\) (c) \({ }^{235} \mathrm{U} \rightarrow{ }^{230} \mathrm{Th}+{ }^{5} \mathrm{He}\) The needed atomic masses are $$ \begin{array}{llll} { }^{232} \mathrm{Th} & 232.0381 \mathrm{u} & { }^{3} \mathrm{He} & 3.0160 \mathrm{u} \\ { }^{231} \mathrm{Th} & 231.0363 \mathrm{u} & { }^{4} \mathrm{He} & 4.0026 \mathrm{u} \\ { }^{230} \mathrm{Th} & 230.0331 \mathrm{u} & { }^{5} \mathrm{He} & 5.0122 \mathrm{u} \\ { }^{235} \mathrm{U} & 235.0429 \mathrm{u} & & \end{array} $$
Step-by-Step Solution
VerifiedKey Concepts
Mass Defect
Using Einstein's famous equation, the mass defect \(\Delta m\) is directly converted into energy through \(E = \Delta m c^2\), where \(c\) is the speed of light.
This energy conversion explains why even a small mass defect can result in a significant energy release, as seen in nuclear decay processes.
Disintegration Energy
In the context of uranium-235 decay, this energy tells us whether the decay process releases or requires energy. When we calculate the disintegration energy, a negative value indicates endothermic reactions, where energy is absorbed.
For instance, in process (a) and (b) of the exercise, \(^{235}\mathrm{U}\) decays require energy to proceed (energies of -10.43 MeV and -3.73 MeV respectively). Conversely, a positive energy, as seen in process (c) with 2.24 MeV, indicates that energy is released, making it an exothermic process.
This concept is crucial for understanding why certain nuclear decay processes occur naturally and which configurations of nucleons are likely to be stable or undergo decay.
Alpha Decay
In the given exercise, one of the scenarios (process b) involves \(^{235}\mathrm{U}\) decaying by emitting an alpha particle to form \([^4\mathrm{He}]\) and \(^{231}\mathrm{Th}\). This kind of decay is particularly likely for heavy nuclides because it achieves a large mass defect and, therefore, releases energy, making it energetically favorable.
Though other types of decay paths are possible, alpha decay stands out due to its lower energy requirement, as illustrated by the calculation yielding -3.73 MeV, which is more achievable than other combinations. This stability makes alpha decay a preferred path for heavy elements attempting to reach a more stable state.