Chapter 2

Introductory Chemistry Atoms First · 168 exercises

Problem 71

Convert the following measured values from scientific notation to standard notation. For each one, indicate the number of significant figures. (a) \(5.60 \times 10^{1} \mathrm{~kg}\) (b) \(2.5 \times 10^{-4} \mathrm{~m}\) (c) \(5.600 \times 10^{6}\) miles (d) \(0.02 \times 10^{2} \mathrm{ft}\)

4 step solution

Problem 73

Using scientific notation, write the measurement \(30 \mathrm{ft}\) as having an uncertainty of: (a) \(\pm 1 \mathrm{ft}\) (b) \(\pm 0.1 \mathrm{ft}\) (c) \(\pm 0.01 \mathrm{ft}\)

4 step solution

Problem 74

Using scientific notation, write the measurement \(2200 \mathrm{ft}\) as having an uncertainty of \(\pm 100 \mathrm{ft}\).

3 step solution

Problem 75

Convert the following numbers from standard notation to scientific notation: (a) 226 (b) \(226.0\) (c) \(0.00000000050\) (d) \(0.3\) (e) \(0.30\) (f) \(900,000,574\) with an uncertainty of \(\pm 1\) million (g) \(900,000,574\) with an uncertainty of \(\pm 100\)

16 step solution

Problem 76

How many significant figures are there in the following measured values, and what is the uncertainty in each measurement? (a) \(0.001 \mathrm{~kg}\) (b) \(0.00010 \mathrm{~m}\) (c) \(102 \mathrm{~L}\) (d) \(2.600 \times 10^{-3} \mathrm{~m}\) (e) \(1.1 \times 10^{6} \mathrm{~km}\)

10 step solution

Problem 77

To the correct number of significant figures, what is the result of adding the measured values 100 in. \(+2\) in. \(+0.001\) in.? What is the uncertainty in the result?

5 step solution

Problem 78

To the correct number of significant figures, what is the product of each mathematical operation? Use scientific notation when necessary. (No units shown means a number is exact.) (a) \(2.30 \mathrm{~cm} \times 2\) (b) \(2 \mathrm{~m} \times 2.000 \mathrm{~m}\) (c) \(1001 \mathrm{~J} \times 10\) (d) \(124 \mathrm{~mm} \div 0.1 \mathrm{~mm}\)

12 step solution

Problem 79

A student walks \(20,450.2 \mathrm{ft}\) to school every day. A mile is defined as \(5280 \mathrm{ft}\). Doing the division \(20,450.2 \mathrm{ft} \div 5280 \mathrm{ft}\) per mile on a calculator gives \(3.873143939\) miles. What, if anything, is wrong with this answer?

3 step solution

Problem 80

Do these calculations using a scientific calculator and report your answers in scientific notation: (a) \(\left(3.33 \times 10^{4} \mathrm{~km}\right)+\left(2.22 \times 10^{5} \mathrm{~km}\right)\) (b) \(\left(2.444 \times 10^{9} \mathrm{~J}\right) \div\left(2.444 \times 10^{-9} \mathrm{~J}\right)\) (c) \(\left(2.34 \times 10^{2} \mathrm{~m}\right)-\left(2.34 \times 10^{1} \mathrm{~m}\right)\) (d) \(\left(4.00 \times 10^{4} \mathrm{~L}\right)+\left(6.00 \times 10^{-1} \mathrm{~L}\right)\)

12 step solution

Problem 81

What is the base SI unit of length? What is the SI unit of yolume?

2 step solution

Problem 82

What are two metric but non-SI units of volume, and why are they more often used than the SI unit of volume?

5 step solution

Problem 83

When is it correct to use \(\mathrm{cm}^{3}\) instead of \(\mathrm{mL}\) ? Explain.

5 step solution

Problem 84

Why was the SI unit system developed by scientists?

5 step solution

Problem 85

Convert each length to meters. Report your answers in scientific notation and watch your significant figures. (a) \(2.31\) gigameters \((\mathrm{Gm})\) (b) \(5.00\) micrometers \((\mu m)\) (c) 1004 millimeters \((\mathrm{mm})\) (d) \(5.00\) picometers \((\mathrm{pm})\) (e) \(0.25\) kilometer \((\mathrm{km})\)

5 step solution

Problem 86

Which is larger, a Celsius degree or a Fahrenheit degree? Explain.

2 step solution

Problem 87

Of the three temperature scales, which can have negative temperatures? For the one(s) that can't, explain why not.

5 step solution

Problem 88

Convert: (a) \(22.5^{\circ} \mathrm{C}\) to Fahrenheit and Kelvin (b) \(-3.00{ }^{\circ} \mathrm{F}\) to Celsius and Kelvin (c) \(100.0^{\circ} \mathrm{C}\) to Kelvin and Fahrenheit (d) \(65.1^{\circ} \mathrm{C}\) to Fahrenheit and Kelvin

8 step solution

Problem 89

How cold does it have to be for water to freeze in \({ }^{\circ} \mathrm{F}\) ? In \({ }^{\circ} \mathrm{C}\) ? In kelvins?

3 step solution

Problem 90

What is the coldest temperature possible in Celsius and Fahrenheit? Give your answers to an uncertainty of plus or minus one-hundredth of a degree.

4 step solution

Problem 93

Using a ruler marked in centimeters and millimeters, a student measures the diameter of a ball to be \(1.5 \mathrm{~cm}\). His partner measures the same ball with the same ruler and comes up with \(1.50\) \(\mathrm{cm}\). Which student used the ruler incorrectly? How did that student use the ruler incorrectly?

4 step solution

Problem 94

The students measure another ball with the ruler in Problem \(2.93\) and determine that its diameter is \(2.55 \mathrm{~cm}\). What is the radius of the ball to the correct number of significant figures?

4 step solution

Problem 95

Define density, and explain why the unit for density is called a derived SI unit.

4 step solution

Problem 99

Using a bathroom scale, a tub, a sponge, and a measuring cup, explain how you would measure your own density.

7 step solution

Problem 100

Two students measure the density of gold. One works with a \(100-g\) bar of pure gold. The other works with a \(200-g\) bar of pure gold. Which student measures the larger density? Explain your answer.

5 step solution

Problem 102

Suppose it takes you \(0.850\) weeks to reach the moon in a space ship. How many seconds does it take for you to get there? Use unit analysis to calculate your answer, and show your work.

7 step solution

Problem 103

A train traveling at \(45.0\) miles \(/ \mathrm{h}\) has to make a trip of \(100.0\) miles. How many minutes will the trip take? Use unit analysis to calculate your answer, and show your work.

5 step solution

Problem 104

You have a great job in which you earn \(\$ 25.50\) per hour. How many dollars do you earn per second? Use unit analysis to calculate your answer, and show your work.

6 step solution

Problem 105

Gold has a density of \(19.3 \mathrm{~g} / \mathrm{mL}\). Suppose you have \(100.0\) glonkins of gold. What volume in liters will the gold occupy? Here are some conversion factors to help you: \(0.911\) ounce per glonkin and \(28.35 \mathrm{~g}\) per ounce. Use unit analysis to calculate your answer, and show your work. Treat both conversion factors as exact.

2 step solution

Problem 106

One liter is equal to \(0.264\) gallon. Suppose you have \(1.000 \times 10^{3} \mathrm{~cm}^{3}\) of water. How many gallons do you have? Use unit analysis to calculate your answer, and show your work. Treat all conversion factors as exact.

4 step solution

Problem 107

The dimensions of a rectangular box are given to be \(10.2 \mathrm{~cm} \times 43.7 \mathrm{~cm} \times 9.56 \times 10^{2} \mathrm{~mm}\). What is its volume in liters? Be careful! The units are not all the same.

4 step solution

Problem 109

You measure one edge of a cube using a meterstick marked in centimeters. Unfortunately, the edge is longer than \(1 \mathrm{~m}\). You mark the \(1-\mathrm{m}\) point on the cube edge with a pen and then, using a \(15-\mathrm{cm}\) ruler marked in millimeters, measure the remaining distance to be \(1.40 \mathrm{~cm}\). (a) What is the length of the edge in centimeters? (b) What is the volume of the cube in cubic centimeters? (Remember, the lengths of all edges of a cube are equal.) Watch your significant figures. Use scientific notation if you have to. (c) The cube has a mass of \(111 \mathrm{~kg} .\) What is its density in grams per milliliter? Watch your significant figures.

3 step solution

Problem 110

A rectangular box measures \(6.00\) in. in length, \(7.00\) in. in width, and \(8.00\) in. in height. What is the volume of the box in liters? \([2.54 \mathrm{~cm}=1\) in.]

5 step solution

Problem 111

An object travels \(80.0 \mathrm{~m} / \mathrm{s}\). How fast is it traveling in miles per hour? \([1 \mathrm{~m}=3.28 \mathrm{ft}, 1\) mile \(=5280 \mathrm{ft}]\)

4 step solution

Problem 112

Why can't you multiply just one side of an equation by something when algebraically rearranging the equation?

6 step solution

Problem 113

(a) Solve the equation \(y=z / x\) for \(x\). (b) Solve the equation \(y=z / 2 x\) for \(x\).

4 step solution

Problem 114

Solve the equation \(y=z-x\) for \(x\).

3 step solution

Problem 115

Solve the equation \(5 x-6=3 x-8\) (find the value of \(x\) that makes this equation true).

3 step solution

Problem 116

The density of a certain liquid is \(1.15 \mathrm{~g} / \mathrm{mL}\). What mass in grams of the liquid is needed to fill a \(50.00\) -mL container? Do this problem by the method of algebraic manipulation, beginning with the equation density \(=\) mass/volume and showing all steps.

5 step solution

Problem 118

Define energy.

4 step solution

Problem 119

How much heat energy is 1 cal? Give your answer in terms of changing the temperature of water.

4 step solution

Problem 120

Convert: (a) \(4.50\) Cal to calories (b) \(600.0\) Cal to kilojoules (c) \(1.000 \mathrm{~J}\) to calories (d) \(50.0\) Cal to joules

4 step solution

Problem 121

Define specific heat.

2 step solution

Problem 122

A \(100.0\) -g block of iron and a \(100.0\) -g block of aluminum are both initially at \(25.0^{\circ} \mathrm{C}\). Both are then warmed to \(100.0^{\circ} \mathrm{C}\). Does one block require more heat energy than the other to reach \(100.0{ }^{\circ} \mathrm{C}\) ? If so, how much more?

5 step solution

Problem 123

How many "big \(\mathrm{C}^{\prime \prime}\) Calories does it take to raise the temperature of \(2.00 \mathrm{~L}\) of water from \(22.0{ }^{\circ} \mathrm{C}\) to \(40.0{ }^{\circ} \mathrm{C} ?\) How many kilojoules? Take the density of water to be \(1.00 \mathrm{~g} / \mathrm{mL}\).

3 step solution

Problem 124

Why is it necessary for a calorimeter to be insulated?

4 step solution

Problem 125

A \(2.50-g\) piece of wood is burned in a calorimeter that contains \(0.200 \mathrm{~kg}\) of water. The burning causes the water temperature to increase from \(22.1^{\circ} \mathrm{C}\) to \(28.7^{\circ} \mathrm{C}\). How much heat energy is released in joules? What is the energy content of the wood in joules per gram of wood?

5 step solution

Problem 126

How many joules of heat energy would it take to raise the temperature of \(2.00\) pounds of iron from \(30.0^{\circ} \mathrm{C}\) to \(90.0^{\circ} \mathrm{C} ?[453.6 \mathrm{~g}=1\) pound \(]\)

3 step solution

Problem 129

Which one of the following expresses the measured value \(1230.0 \mathrm{~m}\) with the correct number of significant figures and appropriate Greek prefix? (a) \(1.23 \mathrm{~km}\) (b) \(1.230 \mathrm{~cm}\) (c) \(1.2300 \mathrm{~km}\) (d) \(1.2300 \mathrm{~mm}\) (e) \(12.3 \mathrm{~km}\)

3 step solution

Problem 130

Convert: (a) \(7.98 \times 10^{23} \mu \mathrm{L}\) to liters (b) \(3.00 \times 10^{-3} \mathrm{mg}\) to grams (c) \(4.21 \times 10^{8} \mathrm{~mL}\) to gallons \(\left[1 \mathrm{~m}^{3}=264\right.\) gallons \(]\)

3 step solution

Problem 131

A metal sphere has a radius \(r\) of \(4.00 \mathrm{~cm}\). What is the volume \(V\) of this sphere in cubic centimeters? The formula for the volume of a sphere is \(V=(4 / 3) \pi r^{3}\), where \(\pi=3.14159 .\)

4 step solution

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