Chapter 2

Chemistry The Molecular Nature of Matter · 76 exercises

Problem 84

Consider the balanced equation for the combustion of hexane, a component of gasoline: $$ 2 \mathrm{C}_{6} \mathrm{H}_{14}+19 \mathrm{O}_{2} \longrightarrow 12 \mathrm{CO}_{2}+14 \mathrm{H}_{2} \mathrm{O} $$ (a) How many atoms of \(\mathrm{C}\) are on each side of the equation? (b) How many atoms of \(\mathrm{H}\) are on each side of the equation? (c) How many atoms of \(\mathrm{O}\) are on each side of the equation?

3 step solution

Problem 89

Use the periodic table, but not Table \(2.2,\) to write the (b) Br, (c) \(\mathrm{Mg},\) (d) \(\mathrm{S},\) and symbols for the ions of (a) \(\mathrm{K}\) (e) Al.

6 step solution

Problem 90

Use the periodic table, but not Table \(2.2,\) to write the symbols for ions of (a) barium, (b) oxygen, (c) fluorine, (d) strontium, and (e) rubidium.

3 step solution

Problem 91

Write formulas for ionic compounds formed between (a) \(\mathrm{Na}\) and \(\mathrm{Br}\), (b) \(\mathrm{K}\) and \(\mathrm{I},(\mathbf{c}) \mathrm{Ba}\) and \(\mathrm{O},\) (d) \(\mathrm{Mg}\) and \(\mathrm{Br}\), (e) \(\mathrm{Al}\) and \(\mathrm{S},\) and \((\mathbf{f}) \mathrm{Ba}\) and \(\mathrm{F}\)

3 step solution

Problem 92

Write formulas for ionic compounds formed between (a) \(\mathrm{Al}\) and \(\mathrm{Br},\) (b) \(\mathrm{Rb}\) and \(\mathrm{I},\) (c) \(\mathrm{Sr}\) and \(\mathrm{S}\), (d) \(\mathrm{Mg}\) and \(\mathrm{N}\), (e) Ga and \(\mathrm{O},\) and \((\mathbf{f}) \mathrm{Sr}\) and \(\mathrm{F}\)

3 step solution

Problem 95

Write formulas for the ionic compounds formed from (a) \(\mathrm{K}^{+}\) and nitrate ion, (b) \(\mathrm{Ca}^{2+}\) and acetate ion, (c) ammonium ion and \(\mathrm{Cl}^{-},\) (d) \(\mathrm{Fe}^{3+}\) and carbonate ion, and (e) \(\mathrm{Mg}^{2+}\) and phosphate ion.

4 step solution

Problem 96

Write formulas for the ionic compounds formed from (a) \(\mathrm{Zn}^{2+}\) and hydroxide ion, (b) \(\mathrm{Ag}^{+}\) and chromate ion, (c) \(\mathrm{Ba}^{2+}\) and sulfite ion, (d) \(\mathrm{Rb}^{+}\) and sulfate ion, and (e) \(\mathrm{Li}^{+}\) and bicarbonate ion.

6 step solution

Problem 98

Write formulas for the ionic compounds formed from \(\mathrm{Cl}^{-}\) and (a) cadmium ion, (b) silver ion, (c) zinc ion, and (d) nickel ion.

8 step solution

Problem 99

Name the following ionic compounds: (a) CaS, (b) AlBr, (c) \(\mathrm{Na}_{3} \mathrm{P}\) (d) \(\mathrm{Ba}_{3} \mathrm{As}_{2}\) (e) \(\mathrm{Rb}_{2} \mathrm{~S}\).

5 step solution

Problem 100

Name the following ionic compounds: (a) \(\mathrm{NaF},\) (b) \(\mathrm{Mg}_{2} \mathrm{C}\) (c) \(\mathrm{Li}_{3} \mathrm{~N}\) (d) \(\mathrm{Al}_{2} \mathrm{O}_{3}\) (e) \(\mathrm{K}_{2} \mathrm{Se}\)

5 step solution

Problem 101

Name the following molecular compounds: (a) \(\mathrm{SiO}_{2}\), (b) \(\mathrm{XeF}_{4}\) (c) \(\mathrm{P}_{4} \mathrm{O}_{10}\) (d) \(\mathrm{Cl}_{2} \mathrm{O}_{7}\)

5 step solution

Problem 103

Name the following ionic compounds using the Stock system: (a) FeS, (b) \(\mathrm{CuO}\) (c) \(\mathrm{SnO}_{2}\), (d) \(\mathrm{CoCl}_{2} \cdot 6 \mathrm{H}_{2} \mathrm{O} .\)

5 step solution

Problem 104

Name the following ionic compounds using the Stock system: (a) \(\mathrm{Mn}_{2} \mathrm{O}_{3}\) (b) \(\mathrm{Hg}_{2} \mathrm{Cl}_{2}\), (c) \(\mathrm{PbS}\), (d) \(\mathrm{CrCl}_{3} \cdot 4 \mathrm{H}_{2} \mathrm{O}\)

8 step solution

Problem 105

Name the following. If necessary, refer to Table 2.4 in Section 2.5. (a) \(\mathrm{NaNO}_{2},\) (b) \(\mathrm{KMnO}_{4},\) (c) \(\mathrm{MgSO}_{4} \cdot 7 \mathrm{H}_{2} \mathrm{O},\) (d) KSCN

4 step solution

Problem 107

Identify each of the following as molecular or ionic, and give its name: (a) \(\mathrm{CrCl}_{2}\) (e) \(\mathrm{KIO}_{3}\) (h) \(\mathrm{AgCN}\) (b) \(\mathrm{S}_{2} \mathrm{Cl}_{2}\) (f) \(\mathrm{P}_{4} \mathrm{O}_{6}\) (i) \(\mathrm{ZnBr}_{2}\) (c) \(\mathrm{SO}_{3}\) (g) \(\mathrm{CaSO}_{3}\) (j) \(\mathrm{H}_{2} \mathrm{Se}\) (d) \(\mathrm{NH}_{4} \mathrm{C}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\)

3 step solution

Problem 108

Identify each of the following as molecular or ionic, and give its name: (a) \(\mathrm{V}\left(\mathrm{NO}_{3}\right)_{3}\) (e) \(\mathrm{GeBr}_{4}\) (h) \(\mathrm{I}_{2} \mathrm{O}_{4}\) (b) \(\mathrm{Au}_{2} \mathrm{~S}\) (f) \(\mathrm{K}_{2} \mathrm{CrO}_{4}\) (i) \(\mathrm{I}_{4} \mathrm{O}_{9}\) (c) \(\mathrm{Au}_{2} \mathrm{~S}_{3}\) (g) \(\mathrm{Fe}(\mathrm{OH})_{2}\) (j) \(\mathrm{P}_{4} \mathrm{Se}_{3}\) (d) \(\mathrm{Co}\left(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\right)_{2}\)

13 step solution

Problem 109

Write formulas for the following. (a) sodium monohydrogen phosphate (b) lithium selenide (c) chromium(III) acetate (d) disulfur decafluoride (e) nickel(II) cyanide (f) iron(III) oxide (g) antimony pentafluoride

9 step solution

Problem 110

Write formulas for the following. (a) dialuminum hexachloride (b) tetraarsenic decaoxide (c) magnesium hydroxide (d) copper(II) bisulfate (e) ammonium thiocyanate (f) potassium thiosulfate (g) diiodine pentaoxide

3 step solution

Problem 111

Write formulas for the following. (a) ammonium sulfide (b) chromium(III) sulfate hexahydrate (c) silicon tetrafluoride (d) molybdenum(IV) sulfide (e) tin(IV) chloride (f) hydrogen selenide (g) tetraphosphorus heptasulfide

7 step solution

Problem 112

Write formulas for the following. (a) mercury(II) acetate (b) barium hydrogen sulfite (c) boron trichloride (d) calcium phosphide (e) magnesium dihydrogen phosphate (f) calcium oxalate (g) xenon tetrafluoride

10 step solution

Problem 116

Which of the following names are incorrect? Write the correct name if possible; if there are several possibilities, write them all. If the name is correct, write the formula. (a) sulfate of barium (b) potassium bromide (c) iron(III) carbonate (d) aluminum(III) phosphate (e) calcium selenide (f) trimagnesium diphosphate (g) dilithium difluoride

4 step solution

Problem 118

The compound \(\mathrm{P}_{2} \mathrm{~S}_{5}\) is used to manufacture safety matches. What is the name of this compound?

3 step solution

Problem 123

What are the formulas for mercury(I) nitrate dihydrate and mercury(II) nitrate monohydrate?

6 step solution

Problem 126

Write the balanced gas phase chemical equation for the reaction of dinitrogen pentoxide with sulfur dioxide to form sulfur trioxide and nitrogen oxide. What small, whole-number ratios are expected for oxygen in the nitrogen oxides and the sulfur oxides?

5 step solution

Problem 131

Around 1750 Benjamin Franklin knew of two opposite types of electric charge, produced by rubbing a glass rod or amber rod with fur. He decided that the charge developed on the glass rod should be the "positive" charge, and from there on charges were defined. What would have changed if Franklin had decided the amber rod was the positive charge?

3 step solution

Problem 133

Spreadsheet applications such as Microsoft Excel can display data in a variety of ways, some of which are shown throughout this book. What method of displaying periodic trends (for example, line graphs, tables, bar graphs, 3-D views, etc.) is most effective for your learning style? Explain your answer by stating why your chosen display is better than the others.

4 step solution

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