Chapter 14

Advanced Problems in Physical Chemistry for Competitive Examinations · 42 exercises

Problem 2

Which element has a relatively more stable nucleus? (a) U (b) \(\mathrm{H}\) (c) Fe (d) Ra

3 step solution

Problem 3

Which of the following is least likely to be stable? (a) \(\mathrm{Ca}^{40}\) (b) \(\mathrm{Al}^{30}\) (c) \(\mathrm{Sn}^{119}\) (d) \(\mathrm{Mn}^{55}\)

4 step solution

Problem 4

The energy required to separate the nucleons from a nucleus is called (a) nuclear energy (b) ionization energy (c) binding energy (d) lattice energy

3 step solution

Problem 5

The value of packing fraction of carbon-12 is (a) positive (b) negative (c) zero (d) infinite

3 step solution

Problem 6

Of the following isotopes, which one is likely to be the most stable? (a) \(\mathrm{Zn}^{63}\) (b) \(\mathrm{Zn}^{67}\) (c) \(\mathrm{Zn}^{71}\) (d) \(\mathrm{Zn}^{64}\)

5 step solution

Problem 8

The largest stable nucleus is (a) \(\mathrm{U}^{238}\) (b) \(\mathrm{B}_{1}^{209}\) (c) \(\mathrm{U}^{235}\) (d) \(\mathrm{Pb}^{206}\)

3 step solution

Problem 11

Among the isotopes of all the elements (only non-radioactive), the \(n / p\) ratio is maximum for (a) \(\mathrm{H}^{1}\) (b) \({ }_{1} \mathrm{H}^{3}\) (c) \({ }_{83} \mathrm{Bi}^{209}\) (d) \({ }_{2} \mathrm{He}^{4}\)

3 step solution

Problem 12

Among the isotopes of all the elements (radioactive as well as non- radioactive), the packing fraction is maximum for (a) \({ }_{1} \mathrm{H}^{1}\) (b) \({ }_{6} \mathrm{C}^{12}\) (c) \({ }_{1} \mathrm{H}^{3}\) (d) \({ }_{26} \mathrm{Fe}^{56}\)

3 step solution

Problem 13

\(\alpha\) -particle is considered identical to He-nucleus because (a) He-nucleus is present in the nuclei of all \(\alpha\) -emitters. (b) He-nucleus has two protons and two neutrons. (c) any sealed vessel containing some \(\alpha\) -emitter is found to contain He gas after some time. (d) He-nucleus is the most stable nucleus.

2 step solution

Problem 14

Emission of one \(\alpha\) -particle from a nucleus results the loss of two protons and two neutrons from the nucleus. These four particles (two protons and two neutrons) comes out from the nucleus (a) all at a time. (b) one by one, both protons followed by both neutrons. (c) one by one, both neutrons followed by both protons. (d) one by one, protons and neutrons alternatively.

3 step solution

Problem 15

In \(\beta\) -decay, an electron comes out from an atom. The electron comes out due to nuclear change, not from the orbit of the atom. It may be explained by the fact that on \(\beta\) -decay, (a) the atomic number increases by one unit. (b) the mass number remains unchanged. (c) the atomic species get changed. (d) the atomic species remains unchanged.

4 step solution

Problem 16

The isotope of \({ }_{90} \mathrm{Ra}^{231}\) can be converted to \({ }_{90} \mathrm{Th}^{227} \mathrm{by}\) (a) One alpha emission (b) Four beta emission (c) Two alpha and two beta emissions (d) One alpha and two beta emissions

6 step solution

Problem 17

When a nucleus reverts from an excited state to the ground state, the energy difference between the two states is emitted as (a) \(\alpha\) -particle (b) \(\beta\) -particle (c) \(\gamma\) -rays (d) neutrino

3 step solution

Problem 18

A free neutron decays to a proton but a free proton does not decay to a neutron. This is because (a) neutron is a composite particle made of a proton and an electron whereas proton is a fundamental particle (b) neutron is a uncharged particle whereas proton is a charged particle (c) neutron has larger rest mass than a proton (d) weak forces can operate in a neutron but not in a proton

5 step solution

Problem 21

A positron is emitted from \(\mathrm{Na}^{23}\) The ratio of the atomic mass and atomie number in the resulting nuclide is (a) \(\frac{22}{10}\) (b) \(\frac{22}{11}\) (c) \(\frac{23}{10}\) (d) \(\frac{23}{12}\)

4 step solution

Problem 25

Consider the beta decay, \(\mathrm{Au}^{198} \rightarrow \mathrm{Hg}^{198^{*}}\), where \(\mathrm{Hg}^{198^{*}}\) represents a mercury nucleus in an excited state at energy \(1.063 \mathrm{MeV}\) above the ground state. What can be the maximum kinetic energy of the electron emitted? The atomic masses of \(\mathrm{Au}^{198}\) and \(\mathrm{Hg}^{198}\) are \(197.968 \mathrm{u}\) and \(197.966 \mathrm{u}\), respec- tively. \((1 \mathrm{u}=931.5 \mathrm{MeV})\) (a) \(0.8 \mathrm{MeV}\) (b) \(1.863 \mathrm{MeV}\) (c) \(1.063 \mathrm{MeV}\) (d) \(1.0 \mathrm{MeV}\)

3 step solution

Problem 26

If the amount of radioactive substance is increases three times, the number of disintegration per unit time will be (a) doubled (b) one-third (c) triple (d) uncharged

3 step solution

Problem 28

If a radioactive element is placed in an evacuated container, its rate of disintegration (a) will be increased (b) will be decreased (c) will change very slightly (d) will remain unchanged

3 step solution

Problem 30

Four vessels \(1,2,3\) and 4 contain respectively, 10 g-atom \(\left(t_{1 / 2}=10 \mathrm{~h}\right), 1 \mathrm{~g}\) -atom \(\left(t_{1 / 2}=5 \mathrm{~h}\right), 5\) g-atom \(\left(t_{1 / 2}=2 \mathrm{~h}\right)\) and 2 g-atom \(\left(t_{1 / 2}=1 \mathrm{~h}\right)\) of different radioactive nuclides. In the beginning, the maximum radioactivity would be exhibited by the vessel (a) 4 (b) 3 (c) 2 (d) 1

3 step solution

Problem 31

If \(8 \mathrm{~g}\) of a radioactive isotope has a halflife of \(10 \mathrm{~h}\). The half-life of \(2 \mathrm{~g}\) of the same substance is (a) \(2.5 \mathrm{~h}\) (b) \(5 \mathrm{~h}\) (c) \(10 \mathrm{~h}\) (d) \(40 \mathrm{~h}\)

3 step solution

Problem 32

If \(N_{\mathrm{o}}\) is the initial number of nuclei, number of nuclei remaining undecayed at the end of \(n^{\text {th }}\) half-life is (a) \(2^{n} \cdot N_{\mathrm{o}}\) (b) \(2^{-n} \cdot N_{\mathrm{o}}\) (c) \(n^{2} \cdot N_{\mathrm{o}}\) (d) \(n^{-2} \cdot N_{\mathrm{o}}\)

4 step solution

Problem 33

A radioactive isotope having a half-life of 3 days was received after 12 days. It was found that there were \(3 \mathrm{~g}\) of the isotope in the container. The initial mass of the isotopes when packed was (a) \(12 \mathrm{~g}\) (b) \(24 \mathrm{~g}\) (c) \(36 \mathrm{~g}\) (d) \(48 \mathrm{~g}\)

3 step solution

Problem 36

A freshly prepared radioactive source of half-life \(2 \mathrm{~h}\), emits radiations of intensity which is 64 times the permissible safe level. The minimum time after which it would be possible to work safely with this source is (a) \(6 \mathrm{~h}\) (b) \(12 \mathrm{~h}\) (c) \(24 \mathrm{~h}\) (d) \(128 \mathrm{~h}\)

4 step solution

Problem 37

Two isotopes 'P' and 'Q' of atomic masses 10 and 20, respectively, are mixed in equal amount, by mass. After 20 day, their mass ratio is found to be \(1: 4 .\) Isotope 'P' has a half-life of 10 days. The half-life of isotope 'Q' is (a) zero (b) 5 day (c) 20 day (d) infinite

4 step solution

Problem 38

A radioactive sample has an initial activity of 28 dpm. Half hour later, the activity is \(14 \mathrm{dpm}\). How many atoms of the radioactive nuclide were there originally? \((\ln 2=0.7)\) (a) 1200 (b) 200 (c) 600 (d) 300

4 step solution

Problem 39

Tritium has a half-life of \(12.26\) years. A \(5.0 \mathrm{ml}\) sample of triturated water has an activity of \(2.4 \times 10^{9} \mathrm{cpm} .\) How many years will it take for the activity to fall to \(3.0 \times 10^{8} \mathrm{cpm} ?\) (a) \(6.13\) (b) \(24.52\) (c) \(36.78\) (d) \(49.04\)

4 step solution

Problem 42

The activity of a certain preparation decreases \(2.5\) times after \(7.0\) days. Find its half-life. (a) \(10.58\) days (b) \(2.65\) days (c) \(5.3\) days (d) \(4.2\) days

5 step solution

Problem 44

An ore of uranium is found to contain \({ }_{92}^{238} \mathrm{U}\) and \({ }_{82}^{206} \mathrm{~Pb}\) in the mass ratio of \(1: 0.1 .\) The half-life period of \({ }_{92}^{238} \mathrm{U}\) is \(4.5 \times 10^{9}\) years. Age of the ore is \((\log 2=0.3, \log\) \(\left.\frac{114.9}{103}=0.048\right)\) (a) \(7.2 \times 10^{8}\) years (b) \(7.2 \times 10^{7}\) years (c) \(7.2 \times 10^{9}\) years (d) \(2.16 \times 10^{9}\) years

7 step solution

Problem 45

In nature a decay chain starts with \(\mathrm{Th}^{232}\) and finally terminates at \(\mathrm{Pb}^{208}\). A thorium ore sample was found to contain \(6.72 \times 10^{-5} \mathrm{ml}\) of \(\mathrm{He}\) (at \(273 \mathrm{~K}\) and \(\left.1 \mathrm{~atm}\right)\) and \(4.64 \times 10^{-7} \mathrm{~g}\) of \(\mathrm{Th}^{232}\). Find the age of the sample assuming that source of He to be only due to decay of \(\mathrm{Th}^{232}\). Also assume complete retention of He within the ore. \(\left(t_{1 / 2}\right.\) of \(\mathrm{Th}^{232}=1.38 \times 10^{10}\) years, \(\log 2=0.3)\) (a) \(2.3 \times 10^{10}\) years (b) \(2.3 \times 10^{9}\) years (c) \(4.6 \times 10^{9}\) years (d) \(9.2 \times 10^{9}\) years

5 step solution

Problem 46

The radioactive series to which \({ }_{88} \mathrm{Ra}^{224}\) belongs is (a) Actinium series (b) Thorium series (c) Uranium series (d) Neptunium series

3 step solution

Problem 47

Actinium series starts with \(\mathrm{A}\) and ends at Z. \(\mathrm{A}\) and \(\mathrm{Z}\) are (a) \({ }_{90} \mathrm{Th}^{232},{ }_{82} \mathrm{~Pb}^{206}\) (b) \({ }_{90} \mathrm{Th}^{235},{ }_{82} \mathrm{~Pb}^{207}\) (c) \({ }_{92} \mathrm{U}^{235},{ }_{82} \mathrm{~Pb}^{207}\) (d) \({ }_{90} \mathrm{Ac}^{227},{ }_{82} \mathrm{~B} \mathrm{i}^{209}\)

4 step solution

Problem 48

Bismuth is the end product of radioactive disintegration series known as (a) \(4 n\) (b) \(4 n+1\) (c) \(4 n+2\) (d) \(4 n+3\)

3 step solution

Problem 49

The end product of \((4 n+2)\) disintegration series the (a) \({ }_{82} \mathrm{~Pb}^{204}\) (b) \({ }_{82} \mathrm{~Pb}^{208}\) (c) \({ }_{82} \mathrm{~Pb}^{209}\) (d) \({ }_{82} \mathrm{~Pb}^{206}\)

5 step solution

Problem 50

Consider the following process of decay, \({ }_{92} \mathrm{U}^{234} \rightarrow{ }_{90} \mathrm{Th}^{230}+{ }_{2} \mathrm{He}^{4} ; t_{1 / 2}=2,50,000\) years \({ }_{90} \mathrm{Th}^{230} \rightarrow{ }_{88} \mathrm{Ra}^{226}+{ }_{2} \mathrm{He}^{4} ; t_{1 / 2}=80,000\) years \({ }_{88} \mathrm{Ra}^{226} \rightarrow{ }_{86} \mathrm{Rn}^{222}+{ }_{2} \mathrm{He}^{4} ; t_{1 / 2}=1600\) years After the above process has occurred for a long time, a state is reached where for every two thorium atoms formed from \({ }_{92} \mathrm{U}^{234}\), one decomposes to form \({ }_{88} \mathrm{Ra}^{226}\) and for every two \({ }_{88} \mathrm{Ra}^{226}\) formed, one decomposes. The ratio of \({ }_{90} \mathrm{Th}^{230}\) to \({ }_{88} \mathrm{Ra}^{226}\) will be (a) \(250000 / 80000\) (b) \(80000 / 1600\) (c) \(250000 / 1600\) (d) \(251600 / 8\)

3 step solution

Problem 52

A radioactive isotope is being produced at a constant rate \(\mathrm{d} N / \mathrm{d} t=R\) in an experiment. The isotope has a half-life, \(t_{1 / 2}\). After a time \(t \gg t_{1 / 2}\), the number of active nuclei will become constant. The value of this constant is (a) \(R\) (b) \(\underline{1}\) (c) \(R / \lambda\) (d) \(\lambda / R\)

5 step solution

Problem 53

The \(t_{1 / 2}\) of \(\mathrm{Pb}^{212}\) is \(8.0 \mathrm{~h}\). It undergoes decay to its daughter (unstable) element \(\mathrm{Bi}^{212}\) of half-life \(60.0\) minute. The time at which daughter element will have maximum activity, is (a) \(205.7 \mathrm{~min}\) (b) \(3.429 \mathrm{~min}\) (c) \(60.0 \mathrm{~min}\) (d) \(67.5 \mathrm{~min}\)

6 step solution

Problem 54

A radionuclide 'A' decays simultaneously into 'B' and ' \(\mathrm{C}\) ', by \(\alpha\) - and \(\beta\) -emission, respectively. The half-lives for the decay are 20 and \(60 \mathrm{~min}\), respectively. The time in which \(87.5 \%\) of ' \(\mathrm{A}\) ' will decay is (a) \(15 \mathrm{~min}\) (b) \(30 \mathrm{~min}\) (c) \(45 \mathrm{~min}\) (d) \(60 \mathrm{~min}\)

8 step solution

Problem 56

The number of neutrons accompanying the formation of \({ }_{54} \mathrm{Xe}^{139}\) and \({ }_{38} \mathrm{Sr}^{94}\) from the absorption of slow neutron by \({ }_{92} \mathrm{U}^{235}\) by nuclear fission is (a) 0 (b) 2 (c) 1 (d) 3

5 step solution

Problem 57

Complete the following nuclear reaction: \({ }_{25} \mathrm{Mn}^{55}(n, \gamma)\) (a) \({ }_{25} \mathrm{Mn}^{55}\) (b) \({ }_{24} \mathrm{Cr}^{56}\) (c) \({ }_{24} \mathrm{Cr}^{54}\) (d) \({ }_{25} \mathrm{Mn}^{56}\)

3 step solution

Problem 58

In the reaction: \({ }_{4} \mathrm{Be}^{9}+\mathrm{X} \rightarrow{ }_{5} \mathrm{~B}^{10}+\gamma, \mathrm{X}\) is (a) proton (b) deuteron (c) \(\alpha\) -particle (d) neutron

4 step solution

Problem 59

Which one of the following particles is used to bombard \({ }_{13} \mathrm{Al}^{27}\) to give \({ }_{15} \mathrm{P}^{30}\) and a neutron? (a) \({ }_{1} \mathrm{H}^{2}\) (b) \(\gamma\) (c) \(\alpha\) (d) \(\beta\)

4 step solution

Problem 65

Bombardment of aluminium be \(\alpha\) -particle leads to its artificial disintegration in two way (i) and (ii) as shown. Products \(\mathrm{X}, \mathrm{Y}\) and \(Z\), respectively, are \({ }_{13}^{27} \mathrm{Al} \longrightarrow{ }_{14}^{30} \mathrm{Si}+\mathrm{X}\) \({ }_{13}^{27} \mathrm{Al} \stackrel{\text { (ii) }}{\longrightarrow}{\underline{\phantom{xx}}}_{15}^{30} \mathrm{P}+\mathrm{Y}\) \({ }_{15}^{30} \mathrm{P} \longrightarrow{ }_{14}^{30} \mathrm{Si}+\mathrm{Z}\) (a) proton, neutron, positron (b) neutron, positron, proton (c) proton, positron, neutron (d) positron, proton, neutron

4 step solution

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