Chapter 14
Advanced Problems in Physical Chemistry for Competitive Examinations · 42 exercises
Problem 2
Which element has a relatively more stable nucleus? (a) U (b) \(\mathrm{H}\) (c) Fe (d) Ra
3 step solution
Problem 3
Which of the following is least likely to be stable? (a) \(\mathrm{Ca}^{40}\) (b) \(\mathrm{Al}^{30}\) (c) \(\mathrm{Sn}^{119}\) (d) \(\mathrm{Mn}^{55}\)
4 step solution
Problem 4
The energy required to separate the nucleons from a nucleus is called (a) nuclear energy (b) ionization energy (c) binding energy (d) lattice energy
3 step solution
Problem 5
The value of packing fraction of carbon-12 is (a) positive (b) negative (c) zero (d) infinite
3 step solution
Problem 6
Of the following isotopes, which one is likely to be the most stable? (a) \(\mathrm{Zn}^{63}\) (b) \(\mathrm{Zn}^{67}\) (c) \(\mathrm{Zn}^{71}\) (d) \(\mathrm{Zn}^{64}\)
5 step solution
Problem 8
The largest stable nucleus is (a) \(\mathrm{U}^{238}\) (b) \(\mathrm{B}_{1}^{209}\) (c) \(\mathrm{U}^{235}\) (d) \(\mathrm{Pb}^{206}\)
3 step solution
Problem 11
Among the isotopes of all the elements (only non-radioactive), the \(n / p\) ratio is maximum for (a) \(\mathrm{H}^{1}\) (b) \({ }_{1} \mathrm{H}^{3}\) (c) \({ }_{83} \mathrm{Bi}^{209}\) (d) \({ }_{2} \mathrm{He}^{4}\)
3 step solution
Problem 12
Among the isotopes of all the elements (radioactive as well as non- radioactive), the packing fraction is maximum for (a) \({ }_{1} \mathrm{H}^{1}\) (b) \({ }_{6} \mathrm{C}^{12}\) (c) \({ }_{1} \mathrm{H}^{3}\) (d) \({ }_{26} \mathrm{Fe}^{56}\)
3 step solution
Problem 13
\(\alpha\) -particle is considered identical to He-nucleus because (a) He-nucleus is present in the nuclei of all \(\alpha\) -emitters. (b) He-nucleus has two protons and two neutrons. (c) any sealed vessel containing some \(\alpha\) -emitter is found to contain He gas after some time. (d) He-nucleus is the most stable nucleus.
2 step solution
Problem 14
Emission of one \(\alpha\) -particle from a nucleus results the loss of two protons and two neutrons from the nucleus. These four particles (two protons and two neutrons) comes out from the nucleus (a) all at a time. (b) one by one, both protons followed by both neutrons. (c) one by one, both neutrons followed by both protons. (d) one by one, protons and neutrons alternatively.
3 step solution
Problem 15
In \(\beta\) -decay, an electron comes out from an atom. The electron comes out due to nuclear change, not from the orbit of the atom. It may be explained by the fact that on \(\beta\) -decay, (a) the atomic number increases by one unit. (b) the mass number remains unchanged. (c) the atomic species get changed. (d) the atomic species remains unchanged.
4 step solution
Problem 16
The isotope of \({ }_{90} \mathrm{Ra}^{231}\) can be converted to \({ }_{90} \mathrm{Th}^{227} \mathrm{by}\) (a) One alpha emission (b) Four beta emission (c) Two alpha and two beta emissions (d) One alpha and two beta emissions
6 step solution
Problem 17
When a nucleus reverts from an excited state to the ground state, the energy difference between the two states is emitted as (a) \(\alpha\) -particle (b) \(\beta\) -particle (c) \(\gamma\) -rays (d) neutrino
3 step solution
Problem 18
A free neutron decays to a proton but a free proton does not decay to a neutron. This is because (a) neutron is a composite particle made of a proton and an electron whereas proton is a fundamental particle (b) neutron is a uncharged particle whereas proton is a charged particle (c) neutron has larger rest mass than a proton (d) weak forces can operate in a neutron but not in a proton
5 step solution
Problem 21
A positron is emitted from \(\mathrm{Na}^{23}\) The ratio of the atomic mass and atomie number in the resulting nuclide is (a) \(\frac{22}{10}\) (b) \(\frac{22}{11}\) (c) \(\frac{23}{10}\) (d) \(\frac{23}{12}\)
4 step solution
Problem 25
Consider the beta decay, \(\mathrm{Au}^{198} \rightarrow \mathrm{Hg}^{198^{*}}\), where \(\mathrm{Hg}^{198^{*}}\) represents a mercury nucleus in an excited state at energy \(1.063 \mathrm{MeV}\) above the ground state. What can be the maximum kinetic energy of the electron emitted? The atomic masses of \(\mathrm{Au}^{198}\) and \(\mathrm{Hg}^{198}\) are \(197.968 \mathrm{u}\) and \(197.966 \mathrm{u}\), respec- tively. \((1 \mathrm{u}=931.5 \mathrm{MeV})\) (a) \(0.8 \mathrm{MeV}\) (b) \(1.863 \mathrm{MeV}\) (c) \(1.063 \mathrm{MeV}\) (d) \(1.0 \mathrm{MeV}\)
3 step solution
Problem 26
If the amount of radioactive substance is increases three times, the number of disintegration per unit time will be (a) doubled (b) one-third (c) triple (d) uncharged
3 step solution
Problem 28
If a radioactive element is placed in an evacuated container, its rate of disintegration (a) will be increased (b) will be decreased (c) will change very slightly (d) will remain unchanged
3 step solution
Problem 30
Four vessels \(1,2,3\) and 4 contain respectively, 10 g-atom \(\left(t_{1 / 2}=10 \mathrm{~h}\right), 1 \mathrm{~g}\) -atom \(\left(t_{1 / 2}=5 \mathrm{~h}\right), 5\) g-atom \(\left(t_{1 / 2}=2 \mathrm{~h}\right)\) and 2 g-atom \(\left(t_{1 / 2}=1 \mathrm{~h}\right)\) of different radioactive nuclides. In the beginning, the maximum radioactivity would be exhibited by the vessel (a) 4 (b) 3 (c) 2 (d) 1
3 step solution
Problem 31
If \(8 \mathrm{~g}\) of a radioactive isotope has a halflife of \(10 \mathrm{~h}\). The half-life of \(2 \mathrm{~g}\) of the same substance is (a) \(2.5 \mathrm{~h}\) (b) \(5 \mathrm{~h}\) (c) \(10 \mathrm{~h}\) (d) \(40 \mathrm{~h}\)
3 step solution
Problem 32
If \(N_{\mathrm{o}}\) is the initial number of nuclei, number of nuclei remaining undecayed at the end of \(n^{\text {th }}\) half-life is (a) \(2^{n} \cdot N_{\mathrm{o}}\) (b) \(2^{-n} \cdot N_{\mathrm{o}}\) (c) \(n^{2} \cdot N_{\mathrm{o}}\) (d) \(n^{-2} \cdot N_{\mathrm{o}}\)
4 step solution
Problem 33
A radioactive isotope having a half-life of 3 days was received after 12 days. It was found that there were \(3 \mathrm{~g}\) of the isotope in the container. The initial mass of the isotopes when packed was (a) \(12 \mathrm{~g}\) (b) \(24 \mathrm{~g}\) (c) \(36 \mathrm{~g}\) (d) \(48 \mathrm{~g}\)
3 step solution
Problem 36
A freshly prepared radioactive source of half-life \(2 \mathrm{~h}\), emits radiations of intensity which is 64 times the permissible safe level. The minimum time after which it would be possible to work safely with this source is (a) \(6 \mathrm{~h}\) (b) \(12 \mathrm{~h}\) (c) \(24 \mathrm{~h}\) (d) \(128 \mathrm{~h}\)
4 step solution
Problem 37
Two isotopes 'P' and 'Q' of atomic masses 10 and 20, respectively, are mixed in equal amount, by mass. After 20 day, their mass ratio is found to be \(1: 4 .\) Isotope 'P' has a half-life of 10 days. The half-life of isotope 'Q' is (a) zero (b) 5 day (c) 20 day (d) infinite
4 step solution
Problem 38
A radioactive sample has an initial activity of 28 dpm. Half hour later, the activity is \(14 \mathrm{dpm}\). How many atoms of the radioactive nuclide were there originally? \((\ln 2=0.7)\) (a) 1200 (b) 200 (c) 600 (d) 300
4 step solution
Problem 39
Tritium has a half-life of \(12.26\) years. A \(5.0 \mathrm{ml}\) sample of triturated water has an activity of \(2.4 \times 10^{9} \mathrm{cpm} .\) How many years will it take for the activity to fall to \(3.0 \times 10^{8} \mathrm{cpm} ?\) (a) \(6.13\) (b) \(24.52\) (c) \(36.78\) (d) \(49.04\)
4 step solution
Problem 42
The activity of a certain preparation decreases \(2.5\) times after \(7.0\) days. Find its half-life. (a) \(10.58\) days (b) \(2.65\) days (c) \(5.3\) days (d) \(4.2\) days
5 step solution
Problem 44
An ore of uranium is found to contain \({ }_{92}^{238} \mathrm{U}\) and \({ }_{82}^{206} \mathrm{~Pb}\) in the mass ratio of \(1: 0.1 .\) The half-life period of \({ }_{92}^{238} \mathrm{U}\) is \(4.5 \times 10^{9}\) years. Age of the ore is \((\log 2=0.3, \log\) \(\left.\frac{114.9}{103}=0.048\right)\) (a) \(7.2 \times 10^{8}\) years (b) \(7.2 \times 10^{7}\) years (c) \(7.2 \times 10^{9}\) years (d) \(2.16 \times 10^{9}\) years
7 step solution
Problem 45
In nature a decay chain starts with \(\mathrm{Th}^{232}\) and finally terminates at \(\mathrm{Pb}^{208}\). A thorium ore sample was found to contain \(6.72 \times 10^{-5} \mathrm{ml}\) of \(\mathrm{He}\) (at \(273 \mathrm{~K}\) and \(\left.1 \mathrm{~atm}\right)\) and \(4.64 \times 10^{-7} \mathrm{~g}\) of \(\mathrm{Th}^{232}\). Find the age of the sample assuming that source of He to be only due to decay of \(\mathrm{Th}^{232}\). Also assume complete retention of He within the ore. \(\left(t_{1 / 2}\right.\) of \(\mathrm{Th}^{232}=1.38 \times 10^{10}\) years, \(\log 2=0.3)\) (a) \(2.3 \times 10^{10}\) years (b) \(2.3 \times 10^{9}\) years (c) \(4.6 \times 10^{9}\) years (d) \(9.2 \times 10^{9}\) years
5 step solution
Problem 46
The radioactive series to which \({ }_{88} \mathrm{Ra}^{224}\) belongs is (a) Actinium series (b) Thorium series (c) Uranium series (d) Neptunium series
3 step solution
Problem 47
Actinium series starts with \(\mathrm{A}\) and ends at Z. \(\mathrm{A}\) and \(\mathrm{Z}\) are (a) \({ }_{90} \mathrm{Th}^{232},{ }_{82} \mathrm{~Pb}^{206}\) (b) \({ }_{90} \mathrm{Th}^{235},{ }_{82} \mathrm{~Pb}^{207}\) (c) \({ }_{92} \mathrm{U}^{235},{ }_{82} \mathrm{~Pb}^{207}\) (d) \({ }_{90} \mathrm{Ac}^{227},{ }_{82} \mathrm{~B} \mathrm{i}^{209}\)
4 step solution
Problem 48
Bismuth is the end product of radioactive disintegration series known as (a) \(4 n\) (b) \(4 n+1\) (c) \(4 n+2\) (d) \(4 n+3\)
3 step solution
Problem 49
The end product of \((4 n+2)\) disintegration series the (a) \({ }_{82} \mathrm{~Pb}^{204}\) (b) \({ }_{82} \mathrm{~Pb}^{208}\) (c) \({ }_{82} \mathrm{~Pb}^{209}\) (d) \({ }_{82} \mathrm{~Pb}^{206}\)
5 step solution
Problem 50
Consider the following process of decay, \({ }_{92} \mathrm{U}^{234} \rightarrow{ }_{90} \mathrm{Th}^{230}+{ }_{2} \mathrm{He}^{4} ; t_{1 / 2}=2,50,000\) years \({ }_{90} \mathrm{Th}^{230} \rightarrow{ }_{88} \mathrm{Ra}^{226}+{ }_{2} \mathrm{He}^{4} ; t_{1 / 2}=80,000\) years \({ }_{88} \mathrm{Ra}^{226} \rightarrow{ }_{86} \mathrm{Rn}^{222}+{ }_{2} \mathrm{He}^{4} ; t_{1 / 2}=1600\) years After the above process has occurred for a long time, a state is reached where for every two thorium atoms formed from \({ }_{92} \mathrm{U}^{234}\), one decomposes to form \({ }_{88} \mathrm{Ra}^{226}\) and for every two \({ }_{88} \mathrm{Ra}^{226}\) formed, one decomposes. The ratio of \({ }_{90} \mathrm{Th}^{230}\) to \({ }_{88} \mathrm{Ra}^{226}\) will be (a) \(250000 / 80000\) (b) \(80000 / 1600\) (c) \(250000 / 1600\) (d) \(251600 / 8\)
3 step solution
Problem 52
A radioactive isotope is being produced at a constant rate \(\mathrm{d} N / \mathrm{d} t=R\) in an experiment. The isotope has a half-life, \(t_{1 / 2}\). After a time \(t \gg t_{1 / 2}\), the number of active nuclei will become constant. The value of this constant is (a) \(R\) (b) \(\underline{1}\) (c) \(R / \lambda\) (d) \(\lambda / R\)
5 step solution
Problem 53
The \(t_{1 / 2}\) of \(\mathrm{Pb}^{212}\) is \(8.0 \mathrm{~h}\). It undergoes decay to its daughter (unstable) element \(\mathrm{Bi}^{212}\) of half-life \(60.0\) minute. The time at which daughter element will have maximum activity, is (a) \(205.7 \mathrm{~min}\) (b) \(3.429 \mathrm{~min}\) (c) \(60.0 \mathrm{~min}\) (d) \(67.5 \mathrm{~min}\)
6 step solution
Problem 54
A radionuclide 'A' decays simultaneously into 'B' and ' \(\mathrm{C}\) ', by \(\alpha\) - and \(\beta\) -emission, respectively. The half-lives for the decay are 20 and \(60 \mathrm{~min}\), respectively. The time in which \(87.5 \%\) of ' \(\mathrm{A}\) ' will decay is (a) \(15 \mathrm{~min}\) (b) \(30 \mathrm{~min}\) (c) \(45 \mathrm{~min}\) (d) \(60 \mathrm{~min}\)
8 step solution
Problem 56
The number of neutrons accompanying the formation of \({ }_{54} \mathrm{Xe}^{139}\) and \({ }_{38} \mathrm{Sr}^{94}\) from the absorption of slow neutron by \({ }_{92} \mathrm{U}^{235}\) by nuclear fission is (a) 0 (b) 2 (c) 1 (d) 3
5 step solution
Problem 57
Complete the following nuclear reaction: \({ }_{25} \mathrm{Mn}^{55}(n, \gamma)\) (a) \({ }_{25} \mathrm{Mn}^{55}\) (b) \({ }_{24} \mathrm{Cr}^{56}\) (c) \({ }_{24} \mathrm{Cr}^{54}\) (d) \({ }_{25} \mathrm{Mn}^{56}\)
3 step solution
Problem 58
In the reaction: \({ }_{4} \mathrm{Be}^{9}+\mathrm{X} \rightarrow{ }_{5} \mathrm{~B}^{10}+\gamma, \mathrm{X}\) is (a) proton (b) deuteron (c) \(\alpha\) -particle (d) neutron
4 step solution
Problem 59
Which one of the following particles is used to bombard \({ }_{13} \mathrm{Al}^{27}\) to give \({ }_{15} \mathrm{P}^{30}\) and a neutron? (a) \({ }_{1} \mathrm{H}^{2}\) (b) \(\gamma\) (c) \(\alpha\) (d) \(\beta\)
4 step solution
Problem 65
Bombardment of aluminium be \(\alpha\) -particle leads to its artificial disintegration in two way (i) and (ii) as shown. Products \(\mathrm{X}, \mathrm{Y}\) and \(Z\), respectively, are \({ }_{13}^{27} \mathrm{Al} \longrightarrow{ }_{14}^{30} \mathrm{Si}+\mathrm{X}\) \({ }_{13}^{27} \mathrm{Al} \stackrel{\text { (ii) }}{\longrightarrow}{\underline{\phantom{xx}}}_{15}^{30} \mathrm{P}+\mathrm{Y}\) \({ }_{15}^{30} \mathrm{P} \longrightarrow{ }_{14}^{30} \mathrm{Si}+\mathrm{Z}\) (a) proton, neutron, positron (b) neutron, positron, proton (c) proton, positron, neutron (d) positron, proton, neutron
4 step solution