Chapter 11

The Critical Micelle Concentration is the concentration at which (a) true solution is formed (b) micellization (c) one molar electrolyte is present per \(1000 \mathrm{~g}\) of solution (d) solute and solution form equilibrium

Colloidal solution of silver is prepared by (a) Bredig's arc method (b) peptization (c) colloidal milk (d) double decomposition method

When a few typical solutes are separated by a particular selective membrane, such as protein particles from blood corpuscles, the process is called (a) exosmosis (b) dialysis (c) transpiration (d) endosmosis

Alum purifies muddy water by (a) absorption (b) dialysis (c) emulsifying properties (d) coagulation

In which of the following Tyndall effect is not observed? (a) gold sol (b) sugar solution (c) emulsions (d) suspension

The movement of colloidal particle under the influence of electric field is called (a) electro dialysis (b) electro osmosis (c) electrolysis (d) electrophoresis

Which of the following has maximum flocculation value for a negatively charge sol? (a) \(\mathrm{BaCl}_{2}\) (b) \(\mathrm{NaCl}\) (c) \(\mathrm{AlCl}_{3}\) (d) \(\mathrm{MgCl}_{2}\)

The capacity of an ion to coagulate a colloidal solution depends upon (a) nature of charge (b) amount of charge (c) its shape (d) both (a) and (b)

Which of the following is used for the destruction of colloids? (a) ultrafiltration (b) adding electrolyte (c) both (a) and (b) (d) dialysis

The movement of colloidal particles towards the oppositely charged electrodes on passing electric current is known as (a) Tyndall effect (b) cataphoresis (c) Brownian movement (d) none of these

Which of the following colloidal solution is used in photography? (a) colloidal silver bromide (b) colloidal gold (c) colloidal silver (d) colloidal sulphur

Cod liver is an example of (a) oil emulsion (b) oil in water emulsion (c) water in oil emulsion (d) water in water emulsion

The efficiency of an enzyme to catalyse a reaction is due to its capacity to (a) reduce the activation energy of the reaction (b) form strong enzyme substrate complex (c) decrease the bond energy of all substrate molecules (d) increase the free energy of the catalyst substrate reaction (e) alter the substrate geometry to fit into the shape of the enzyme molecule.

An emulsifier is a substance which (a) stabilizes the emulsion (b) coagulates the emulsion (c) retards the dispersion of liquid in liquid (d) causes homogenesis of emulsion

The process of separating cream from milk is called (a) emulsification (b) demulsification (c) emulsions (d) electro-osmosis

Which of the following process is responsible for the digestion of fats in the intestines? (a) electro-osmosis (b) demulsification (c) electrophoresis (d) emulsification

The ability of a catalyst to accelerate the chemical reaction is known as (a) selectivity (b) activity (c) positive catalysis (d) negative catalysis

A catalyst in a chemical reaction (a) decreases rate constant of the reaction (b) reduces enthalpy of the reaction (c) does not affect equilibrium constant of the reaction (d) increases activation energy of the reaction

Homogeneous catalysis implies that (a) reactants and products must be in the same phase (b) reactants and catalyst must be in the same phase (c) composition of the reaction mixture must be homogeneous throughout (d) products and the catalyst must be in the same phase

In homogeneous catalytic reactions, the rate of reaction (a) depends upon the concentration of catalyst (b) depends upon physical state of catalyst (c) is independent of the physical state of catalyst (d) is independent of the concentration of catalyst

Which of the following is an example of homogeneous catalysis? (a) oxidation of \(\mathrm{SO}_{2}\) to \(\mathrm{SO}_{3}\) in the contact process (b) manufacture of \(\mathrm{NH}_{3}\) by Haber's process (c) oxidation of \(\mathrm{SO}_{2}\) to \(\mathrm{SO}_{3}\) in the lead chamber process (d) oxidation of \(\mathrm{NH}_{3}\) to \(\mathrm{NO}\) in Ostwald's process

In the reaction \(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}(\mathrm{~s})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \stackrel{\mathrm{Dil} \mathrm{H}_{2} \mathrm{SO}}{\leftrightarrow} \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\) (aq) \(+\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(\mathrm{aq})\) dilute \(\mathrm{H}_{2} \mathrm{SO}_{4}\) acts as (a) homogeneous catalyst (b) heterogenous catalyst (c) heterogeneous reactant (d) homogeneous reactant

Which of the following kinds of catalysis can be explained by the adsorption theory? (a) Enzyme catalysis (b) Homogeneous catalysis (c) Acid base catalysis (d) Heterogeneous catalysis

Which of the following is an example of heterogeneous catalyst? (a) \(2 \mathrm{SO}_{2}+\mathrm{O}_{2}+2 \mathrm{H}_{2} \mathrm{O} \longrightarrow 2 \mathrm{H}_{2} \mathrm{SO}_{4}\) (b) \(2 \mathrm{H}_{2} \mathrm{O}_{2}(1)+\mathrm{MnO}_{2}(\mathrm{~s}) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2}\) (c) \(2 \mathrm{H}_{2} \mathrm{O}_{2}(\mathrm{aq}) \stackrel{\mathrm{FeCl}_{3}}{\longrightarrow} 2 \mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2}\) (d) sucrose \(+\mathrm{H}_{2} \mathrm{O} \stackrel{\mathrm{H}^{+}}{\longrightarrow}\) glucose \(+\) fructose

The process, which is catalysed by one of the products, is called (a) acid base catalysis (b) negative catalysis (c) positive catalysis (d) auto catalysis

In case of auto catalysis (a) reactant catalyses (b) product catalyses (c) solvent catalyses (d) heat produced in the reaction catalyses

A biological catalyst is essentially (a) a carbohydrate (b) an enzyme (c) a nitrogen molecules (d) an amino acid

During micelle formation in the solution of surfactants (a) enthalpy change is positive but entropy change is negative (b) both the enthalpy and entropy are negative (c) enthalpy change is negative but entropy change is positive (d) both the enthalpy and entropy changes are positive

Which of the following is used as a catalyst for preparing Grignard reagent? (a) manganese dioxide (b) iron powder (c) activated charcoal (d) dry ether

Which of the following colloidal solution is prepared when very dilute solution of ferric chloride reacts with potassium ferrocyanide? (a) Prussian blue (b) Arsenic sulphide (c) Ferric hydroxide (d) Extrinsic colloid

Adsorption is a phenomenon, in which a substance (a) goes into the body of some other substance (b) accumulates on the surface of some other substance (c) remains close to some other substance (d) does not accumulate on the surface of some other substance

Which of the following statement is wrong about chemisorption? (1) it is reversible in nature (2) it is specific in nature (3) it first increases with increase in temperature and then pressure (4) it involves the formation of a compound on the surface of the solid adsorbent (a) 1 only (b) 2 and 3 (c) 1 and 3 (d) 2 and 4

The adsorption of solids, from a solution is called (a) chemical adsorption (b) physical adsorption (c) positive adsorption (d) negative adsorption

Which of the following is not a characteristic of chemisorption? (a) adsorption is specific (b) adsorption is irreversible (c) adsorption is a multimolecular layer (d) \(\Delta \mathrm{H}\) is of the order of \(400 \mathrm{~kJ}\)

Eosine used to detect the end point of precipitation titration by adsorption is called (a) absorption indicator (b) adsorption indicator (c) normal indicator (d) chemical indicator

The amount of gas adsorbed physically on charcoal (a) increases with pressure and decreases with temperature (b) increases with temperature and decreases with pressure (c) increases with temperature and pressure (d) increases either temperature or pressure.

The chemical adsorption (a) decreases with increase of temperature (b) increase with increase of temperature (c) first increases and then decreases with increase of temperature (d) first decreases and then increases with increase of temperature

Freundlich adsorption isotherm gives a straight line on plotting (a) \(\mathrm{x} / \mathrm{m}\) vs \(\mathrm{P}\) (b) \(\log \mathrm{x} / \mathrm{m}\) vs \(\mathrm{P}\) (c) \(\log \mathrm{x} / \mathrm{m}\) vs \(\log \mathrm{P}\) (d) \(\mathrm{x} / \mathrm{m} \mathrm{vs} 1 / \mathrm{P}\)

A graph between the amount adsorbed \((\mathrm{x} / \mathrm{m})\) and temperature at a constant pressure is called (a) adsorption isobar (b) adsorption isostere (c) adsorption isochore (d) adsorption isotherm

A graph of adsorption isobar of chemisorption shows that adsorption (a) first decreases with temperature and then increases (b) first increases with temperature and then decreases (c) increases with temperature (d) decreases with temperature

The concentration of electrolyte required to coagulate a given amount of \(\mathrm{As}_{2} \mathrm{~S}_{3}\) solution is minimum in case of (a) potassium sulphate (b) aluminium nitrate (c) magnesium nitrate (d) potassium nitrate

Which of the following colloidal solution is commonly used as a germ killer? (a) colloidal sulphur (b) colloidal gold (c) colloidal silver (d) colloidal antimony

Colloidal solution commonly used in the treatment of eye disease is (a) colloidal silver (b) colloidal gold (c) colloidal antimony (d) colloidal sulphur

The bleeding from a wound is stopped by the application of ferric chloride as (a) blood starts flowing in the opposite direction (b) ferric chloride seals the blood vessels (c) blood reacts and a solid is formed which seals the blood vessels (d) blood is coagulated and the blood vessels are sealed.

According to the adsorption theory of catalysis, the speed of the reaction increases because (a) adsorption produces heat which increases the speed of the reaction (b) adsorption lowers the activation energy of the reaction (c) the concentration of reactant molecules at the active centres of the catalyst becomes high due to adsorption (d) in the process of adsorption, the activation energy of the molecules becomes large

A plot of \(\log \mathrm{x} / \mathrm{m}\) versus log \(\mathrm{P}\) for the adsorption of a gas on a solid gives a straight line with slope equal to (a) \(1 / \mathrm{n}\) (b) \(\log \mathrm{K}\) (c) \(-\log \mathrm{K}\) (d) \(\mathrm{n}\)

Which one of the following is not a surfactant? (a) \(\mathrm{CH}_{3}-\left(\mathrm{CH}_{2}\right)_{15}-\mathrm{N}^{+}-\mathrm{CH}_{3} \mathrm{Br}^{-}\) (b) \(\mathrm{CH}_{3}-\left(\mathrm{CH}_{2}\right)_{14}-\mathrm{CH}_{2}-\mathrm{NH}_{2}\) (c) \(\mathrm{CH}_{3}-\left(\mathrm{CH}_{2}\right)_{16}-\mathrm{CH}_{2} \mathrm{OSO}_{2}^{-} \mathrm{Na}^{+}\) (d) \(\mathrm{OHC}-\left(\mathrm{CH}_{2}\right)_{14}-\mathrm{CH}_{2}-\mathrm{COO}^{-} \mathrm{Na}^{+}\)

Which one of the following reactions is an example of heterogeneous catalysis? (a) \(2 \mathrm{CO}(\mathrm{g})+\mathrm{O}_{2}(\mathrm{~g}) \stackrel{\mathrm{NO}(\mathrm{g})}{\longrightarrow} 2 \mathrm{CO}_{2}\) (b) \(2 \mathrm{SO}_{2}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g}) \stackrel{\mathrm{NO}(\mathrm{g})}{\longrightarrow} 2 \mathrm{SO}_{3}\) (c) \(2 \mathrm{CO}(\mathrm{g})+\mathrm{O}_{2}(\mathrm{~g}) \stackrel{\mathrm{Pt}(\mathrm{S})}{\longrightarrow} 2 \mathrm{CO}_{2}\) (d) \(\mathrm{CH}_{3} \mathrm{CHO}(\mathrm{g}) \stackrel{\mathrm{I}_{2}(\mathrm{~g})}{\longrightarrow} \mathrm{CH}_{4}+\mathrm{CO}\)

Which of the following is incorrect? (1) Catalyst undergoes permanent chemical change. (2) Particle size of solute in true solutions is \(10^{-3} \mathrm{~m}\). (3) Starch solution is a hydrosol. (4) Hydrolysis of liquid ester in the presence of mineral acid is an example of heterogeneous catalysis reactions. (a) 1,2 and 3 (b) 2 and 3 (c) 1,2 and 4 (d) 2,3 and 4

Which of the following is an example of homogeneous catalysis reaction? (1) \(2 \mathrm{SO}_{2}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g}) \stackrel{\mathrm{NO}(\mathrm{g})}{\longrightarrow} 2 \mathrm{SO}_{3}(\mathrm{~g})\) (2) Hydrolysis of aqueous sucrose solution in the presence of aqueous mineral acid (3) \(2 \mathrm{H}_{2} \mathrm{O}_{2}(1) \stackrel{\mathrm{Pt}(\mathrm{s})}{\longrightarrow} 2 \mathrm{H}_{2}(\mathrm{l})+\mathrm{O}_{2}(\mathrm{~g})\) (4) hydrolysis of liquid ester in the presence of aqueous mineral acid (a) 2 and 4 (b) 2 and 3 (c) 1,2 and 3 (d) 1,2 and 4