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TextbooksChemistryChemical Principles in the LaboratoryChapter 9

Chapter 9

Chemical Principles in the Laboratory · 1 exercises

Problem 1

A student weighed an empty flask and stopper and found the mass to be \(53.256 \mathrm{g}\). She then added about five milliliters of an unknown liquid and heated the flask (in a boiling-water bath) to \(98.8^{\circ} \mathrm{C}\). After all the liquid had vaporized, she removed the flask from the bath, stoppered it, and let it cool. Once it had cooled, she momentarily removed the stopper, then replaced it and weighed the flask and condensed vapor, obtaining a mass of \(53.870 \mathrm{g}\). The volume of the flask was known to be \(271.1 \mathrm{mL}\). The absolute atmospheric pressure in the laboratory on that day was \(728 \mathrm{mm}\) Hg. a. What was the pressure of the vapor in the flask in atm? \(P=\)___________atm b. What was the temperature of the vapor in \(\mathrm{K}\) ? What was the volume of the flask in liters? \(T=\)___________ \(\mathbf{K}\) \(\quad\) \(V=\)___________\(\mathbf{L}\) c. What was the mass of condensed vapor that was present in the flask? \(m=\)__________grams d. How many moles of condensed vapor were present? \(n=\)__________moles e. What is the mass of one mole of vapor (Eq. 2)? \(M M=\)__________\(g /\) mole

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