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TextbooksChemistryChemical Principles in the LaboratoryChapter 36

Chapter 36

Chemical Principles in the Laboratory · 1 exercises

Problem 3

Why would it be unwise to simply add 10 drops of \(6 \mathrm{M}\) HCl immediately in Step \(1 ?\) What could go wrong? A solution may contain \(A g^{+}, P b^{2+},\) and/or \(H g_{2}^{2+} .\) A white precipitate forms on addition of 6 M HCI. None of the precipitate dissolves in hot water. The precipitate turns gray upon addition of ammonia. Which of the Group I ions are present, which are absent, and which remain undetermined? State your reasoning. Note: For "paper unknowns" such as this one, confirmatory tests are usually not included, and you do not need to provide any. The information provided here, without confirmatory tests, is sufficient to clearly indicate the presence or absence of some of the Group I ions studied in this experiment, while leaving others in doubt. Present______ Absent______ In doubt______

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