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TextbooksChemistryChemical Principles in the LaboratoryChapter 37

Chapter 37

Chemical Principles in the Laboratory · 1 exercises

Problem 3

A solution that may contain \(\mathrm{Cu}^{2+}, \mathrm{Bi}^{3+}, \mathrm{Sn}^{4+},\) or \(\mathrm{Sb}^{3+}\) ions is treated with thioacetamide in an acid medium. The black precipitate that forms is partly soluble in strongly alkaline solution. The precipitate that remains is soluble in \(6 \mathrm{M} \mathrm{HNO}_{3}\) and gives only a blue solution on treatment with excess \(\mathrm{NH}_{3}\). The alkaline solution, when acidified, produces an orange precipitate. On the basis of this information, which ions are present, which are absent, and which are still in doubt? (As with Group I, evidence other than confirmatory tests may show the presence or absence of an ion.) Present ____________ Absent ____________ In doubt ____________

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