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TextbooksChemistryChemical Principles in the LaboratoryChapter 19

Chapter 19

Chemical Principles in the Laboratory · 1 exercises

Problem 1

Methyl orange, HMO, is a common acid-base indicator. In solution it ionizes according to the equation: (EQUATION CAN'T COPY) If methyl orange is added to distilled water, the solution turns yellow. If a drop or two of \(6 \mathrm{M}\) HCl is added to the yellow solution, it turns red. If to that solution one adds a few drops of \(6 \mathrm{M} \mathrm{NaOH}\) the color reverts to yellow. a. Why does adding \(6 \mathrm{M}\) HCl to the yellow solution of methyl orange tend to cause the color to change to red? (Note that in solution HCl exists as \(\mathrm{H}^{+}\) and \(\mathrm{Cl}^{-}\) ions.) b. Why does adding \(6 \mathrm{M}\) NaOH to the red solution tend to make it turn back to yellow? (Note that in solution NaOH exists as Na' and OH- ions. How does increasing [OH-] shift Reaction 3 in the discussion section? How would the resulting change in \(\left[\mathrm{H}^{+}\right]\) affect the dissociation reaction of HMO?)

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