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TextbooksChemistryChemical Principles in the LaboratoryChapter 8

Chapter 8

Chemical Principles in the Laboratory · 1 exercises

Problem 2

In this experiment a student found that when she increased the temperature of a \(550 \mathrm{mL}\) sample of air from \(22.3^{\circ} \mathrm{C}\) to \(29.7^{\circ} \mathrm{C},\) the pressure of the air went from \(1009 \mathrm{cm} \mathrm{H}_{2} \mathrm{O}\) up to \(1033 \mathrm{cm} \mathrm{H}_{2} \mathrm{O}\). Since the air expands linearly with temperature, the equation relating \(P\) to \(t\) is of the form: $$P=m t+b$$ a. What is the slope of the line? (Find the change in \(P\) divided by the change in \(t\).) \(m=\)_____ \(\mathrm{cm} \mathrm{H}_{2} \mathrm{O} /^{\circ} \mathrm{C}\) b. Find the value of \(b .\) (Substitute known values of \(P\) and \(t\) into Equation 9 and solve for \(b\).)\(b=\)_____ c. Express Equation 9 in terms of the values of \(m\) and \(b\). \(P=\) d. At what temperature \(t\) will \(P\) become zero? \(P=0 \quad\) at \(\quad t=\)_____ \(^{\circ} \mathrm{C}=t_{\mathrm{o}}=-A\) e. The temperature in Part d is the absolute zero of temperature. Lord Kelvin suggested that we set up a scale on which that temperature is 0 K. On that scale, \(T=t+A\). Show that, on the Kelvin scale, your equation reduces to \(P=m T\).

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