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TextbooksChemistryChemical Principles in the LaboratoryChapter 14

Chapter 14

Chemical Principles in the Laboratory · 1 exercises

Problem 2

When \(2.0 \mathrm{g}\) of \(\mathrm{NaOH}\) were dissolved in \(53.0 \mathrm{g}\) water in a calorimeter at \(24.0^{\circ} \mathrm{C}\), the temperature of the solution went up to \(33.7^{\circ} \mathrm{C}\). a. Is this solution reaction exothermic? ______ Why? b. Calculate \(q_{H_{2} o},\) using Eq. 1 _______ joules c. Find \(\Delta H\) for the reaction as it occurred in the calorimeter (Eq. 5 ). \(\Delta H=\) ________ joules d. Find \(\Delta H\) for the solution of \(1.00 \mathrm{g} \mathrm{NaOH}\) in water. \(\Delta H=\) _______ joules/g e. Find \(\Delta H\) for the solution of one mole \(\mathrm{NaOH}\) in water. \(\Delta H=\) _______ joules/mole f. Given that NaOH exists as \(\mathrm{Na}^{+}\) and \(\mathrm{OH}^{-}\) ions in solution, write the equation for the reaction that occurs when \(\mathrm{NaOH}\) is dissolved in water. g. Using cnthalpies of formation as given in thermodynamic tables, calculate \(\Delta H\) for the reaction in Part f and compare your answer with the result you obtained in Part e.

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