Q54 E

Question

There are two different substances with the formula C3H6. Draw both, and tell how they differ.

Step-by-Step Solution

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Answer


H2C=CH−CH3                      

                                                 

Propene                                  Cyclopropane

       

The two substances are different because one compound has a double bond, and one has a ring.


1Structural Isomerism

Structural isomers are those isomers in which the atoms are completely arranged in a different order with the same molecular formulas. These are the molecules having the same kind of molecular formula with different connectivities depending upon the order they are put together.

The structural isomerism is also called as constitutional isomerism as per the IUPAC. It is a kind of isomerism where the molecule have the same molecular formula with different orders and bonding, as opposed to that of stereoisomerism.

2Types of structural isomerism

There are three types of structural isomerism

Chain Isomerism- Chain isomerism occurs when there is difference in the atomic arrangement of the carbon to carbon chain of molecule. This phenomena is also called as skeletal isomerism. Example butane and 2-methyl propane.

Position Isomerism- positional isomerism arises when there is difference in the position occupied by substituent atom or group of the atoms or due to unsaturation occurring in chain.

Functional Group Isomerism- The functional group isomerism occurs when there is a presence of the odd form of functional group with same molecular formula. For example dimethyl ether and ethanol have same molecular formula C2H6O but different functional groups.

3Differ two compounds which having same molecular formula C 3 H 6 by structural isomerism.

   H2C=CH−CH3                                                 

 

     Propene                                         Cyclopropane

Cyclopropane and propene are organic compounds having only carbon and hydrogen atom and same molecular formula. The key difference between cyclopropane and propene is that cyclopropane is cyclic alkane, whereas propene is an alkene.