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Q23-10P

Question

What product would you expect to obtain from the base treatment of 

1,6-cyclo-decanedione?

Step-by-Step Solution

Verified
Answer

It gives seven-member ring fused with the five-member ring.

1Step 1: Intramolecular aldol condensation:


2Step 2: Removal of a water molecule on heating and formation of double bond:


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Other exercises in this chapter

Q10P
What product would you expect to obtain from the base treatment of  1,6-cyclo-decanedione?
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Q23-9P
Treatment of a 1,3-diketone such as 2,4-pentanedione with base does not give an aldol condensation product. Explain.
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Q11P
Show the products you would expect to obtain by Claisen condensation of the following esters: (a) CH3CHCH2CO2Et (b) Ethyl phenylacetate (c) Ethyl cyclohexy
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Q12P
As shown in Figures 23-4, the Claisen reaction is reversible. That is, a 𝛃-keto ester can be cleaved by base into two fragments. Using curved arrows to in
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