Q17.1E

Question

If a 2.5 A current is run through a circuit for 35 minutes, how many coulombs of charge moved through the circuit?

Step-by-Step Solution

Verified
Answer

The charge moving through the circuit is 5250C.

1Step1: Define current
  • Current is defined as the rate of charge passing through a circuit. It is mathematically represented as:

                          \(I = \frac{Q}{t}\)

  • Here, I is the current, Q is the charge, and t is the time. 
  • The SI unit of current is Ampere, denoted by symbol A. 
  • Thus, 1A current means 1C of charge passes through a wire every 1 second. Or, \({\bf{1\;A = }}\frac{{{\bf{1C}}}}{{{\bf{1\;s}}}}\)
2Step 2: Determine the charge through the circuit

The current passing through the wire is 2.5A and time is 35 min.

 

Calculation:

 

The current is related to charge and time as follows:

\({\rm{I = }}\frac{{\rm{Q}}}{{\rm{t}}}\)

Thus, charge can be calculated from current as:

\({\rm{Q  =  I \times t}}\)

Putting the values,

\(\begin{array}{l}{\rm{Q  =    (2}}{\rm{.5\;A)(35\;min)}}\left( {\frac{{{\rm{60\;s}}}}{{{\rm{1\;min}}}}} \right){\rm{ =  5250A}}\\{\rm{s  =   5250C}}\end{array}\)

 

\(\Delta G_{f\left( {N{O_L}} \right)}^^\circ  = 51.30\;{\rm{kJ}}/{\rm{mol}}\)

\(\Delta {G_{f\left( {\;{{\rm{N}}_2}{{\rm{O}}_4}} \right)}} = 99.8\;{\rm{kJ}}/{\rm{mol}}\)

 

We need to calculate the equilibrium constant for the dissociation of dintrogen tetroxide \(\left( {{{\rm{N}}_2}{{\rm{O}}_4}} \right)\)

 

\(\Delta {G^^\circ } = \sum \Delta  G_f^^\circ \) (products) \( - \sum \Delta  G_f^^\circ \) (reactants)

\( = 2\Delta G_{{N_2}}^^\circ  - \Delta {G^^\circ }^^\circ {O_4}\)

\( = 2 \times 51.3 - 99.8\)

\( = 2.8\;{\rm{kJ}}/{\mathop{\rm mo}\nolimits} l\quad (1\;{\rm{kJ}} = 1000\;{\rm{J}})\)

or\(2800\;{\rm{J}}/\) mol

\(\Delta {G^^\circ } =  - RT\ln {K_{eq}}\)

\( = \frac{{ - 2800}}{{8.314 \times 298}}\)

\(\ln {k_{{\rm{eq }}}} =  - 1.130\)

or\({K_{eq}} = {e^{ - 1.130}}\)

\({K_{{\rm{eq }}}} = 0.30\)