Q. 6.80 - An Introduction to General, Organic, and Biological Chemistry

Question

Why is ${\mathrm{CCl}}_4$ a nonpolar molecule, but ${\mathrm{PCl}}_3$ is a polar molecule?

Step-by-Step Solution

Answer

Because ${\mathrm{CCl}}_4$ is tetrahedral whereas ${\mathrm{PCl}}_3$ is pyramidial. That's why ${\mathrm{CCl}}_4$ a nonpolar molecule, but ${\mathrm{PCl}}_3$ is a polar molecule.

Step 1 : Given information

We are to find why ${\mathrm{CCl}}_4$ is nonpolar whereas ${\mathrm{PCl}}_3$ is polar.

Step 2 : Simplify

Each molecule's bonding orbitals are arranged in a tetrahedron; the only difference is that  ${\mathrm{CCl}}_4$has enough atoms linked to the carbon to make the molecule completely tetrahedral.
Each chlorine in ${\mathrm{CCl}}_4$ is slightly negative, yet the molecule's symmetry means that the molecule is non-polar.
The steric number of phosphorus in ${\mathrm{PCl}}_3$ is $4$ much as carbon in ${\mathrm{CCl}}_4$However, four atoms encircle carbon.
The phosphorus in ${\mathrm{PCl}}_3$ has a lone pair and three data-custom-editor="chemistry" $\mathrm{Cl}$ surrounding it.The tetrahedron cannot be completed because there are insufficient bound atoms.
The phosphorus atoms are at the top of the ${\mathrm{PCl}}_3$ molecule, while the chlorine atoms are at the bottom.