Problem 97
Question
Radiocarbon Dating Two isotopes of carbon, \({ }^{12} \mathrm{C},\) which is stable, and \({ }^{14} \mathrm{C},\) which decays exponentially with a 5700 -year half-life, are found in a known fixed ratio in living matter. After death, carbon is no longer metabolized, and the amount \(m(t)\) of \({ }^{14} \mathrm{C}\) decreases due to radioactive decay. In the analysis of a sample performed \(T\) years after death, the mass of \({ }^{12} \mathrm{C}\), unchanged since death, can be used to determine the mass \(m_{0}\) of \({ }^{14} \mathrm{C}\) that the sample had at the moment of death. The time \(T\) since death can then be calculated from the law of exponential decay and the measurement of \(m(T)\). Use this information for solving Exercises \(95-98\). Prehistoric cave art has recently been found in a number of new locations. At Chauvet, France, the amount of \({ }^{14} \mathrm{C}\) in some charcoal samples was determined to be \(0.0879 \cdot m_{0}\). Ahout how old are the cave drawings?
Step-by-Step Solution
VerifiedKey Concepts
Exponential Decay
Exponential decay can be represented mathematically by the equation: \[m(t) = m_0 \cdot e^{-\lambda t}\]where:
- \(m(t)\) is the remaining amount of the substance at time \(t\).
- \(m_0\) is the initial amount at the starting time (usually at the time of death for radiocarbon).
- \(e\) is the base of the natural logarithms, approximately equal to 2.718.
- \(\lambda\) is the decay constant (a topic we'll discuss in detail soon).
Half-life
This property is pivotal in determining the timeline of decay in radiocarbon dating.
- For \(^{14} \mathrm{C}\), the half-life is approximately 5700 years. This length of time gives scientists a window to measure ages up to about 50,000 years.
- Since half of the substance decays every 5700 years, the concept of half-life helps to easily estimate how much of the original \(^{14} \mathrm{C}\) remains at any given point in time.
Decay Constant
For any radioactive isotope, the decay constant relates to the half-life using the formula: \[\lambda = \frac{\ln(2)}{\text{half-life}}\]where \(\ln(2)\) is the natural logarithm of 2, which is approximately 0.693.
For \(^{14} \mathrm{C}\), with a half-life of 5700 years, \(\lambda\) is calculated as follows:
- \(\lambda = \frac{\ln(2)}{5700} \approx 1.216 \times 10^{-4}\) per year.