Problem 95
Question
The radionuclide \({ }^{32} \mathrm{P}\left(T_{1 / 2}=14.28 \mathrm{~d}\right)\) is often used as a tracer to follow the course of biochemical reactions involving phosphorus. (a) If the counting rate in a particular experimental setup is initially 3050 counts/s, how much time will the rate take to fall to 170 counts/s? (b) A solution containing \({ }^{32} \mathrm{P}\) is fed to the root system of an experimental tomato plant, and the \({ }^{32} \mathrm{P}\) activity in a leaf is measured 3.48 days later. By what factor must this reading be multiplied to correct for the decay that has occurred since the experiment began?
Step-by-Step Solution
Verified Answer
(a) 55.60 days, (b) Correction factor is 1.188.
1Step 1: Understand the decay formula
The decay of a radioactive substance can be described by the formula: \[N(t) = N_0 \left( \frac{1}{2} \right)^{t/T_{1/2}}\]where \(N(t)\) is the remaining quantity at time \(t\), \(N_0\) is the initial quantity, and \(T_{1/2}\) is the half-life.
2Step 2: Calculate decay time (Part a)
Using the formula, we need to solve for \(t\) such that the initial rate of 3050 counts/s reduces to 170 counts/s.\[3050 \left( \frac{1}{2} \right)^{t/14.28} = 170\]Divide both sides by 3050:\[ \left( \frac{1}{2} \right)^{t/14.28} = \frac{170}{3050}\]This simplifies to:\[ \left( \frac{1}{2} \right)^{t/14.28} = 0.0557\]Take the logarithm of both sides to solve for \(t\):\[ \frac{t}{14.28} \log \left( \frac{1}{2} \right) = \log(0.0557)\]Solving for \(t\):\[ t = 14.28 \times \frac{\log(0.0557)}{\log(0.5)}\]\[ t \approx 55.60 \text{ days}\]
3Step 3: Determine decay factor (Part b)
The correction factor for decay can be calculated by the formula given the time elapsed and the half-life.\[ \text{Correction factor} = \left( \frac{1}{2} \right)^{-t/T_{1/2}} \]Here, \(t = 3.48\) days. Substituting the values:\[ \text{Correction factor} = \left( \frac{1}{2} \right)^{-3.48/14.28}\]Calculating gives:\[ \text{Correction factor} \approx 1.188 \]
4Step 4: Final Answer
The time for the rate to decrease from 3050 counts/s to 170 counts/s is approximately 55.60 days. For part b, the correction factor for 3.48 days decay is approximately 1.188.
Key Concepts
half-liferadiation counting ratetracer in biochemical reactions
half-life
The concept of half-life is a fundamental aspect of radioactive decay and is crucial for understanding how radionuclides like \(^{32} \text{P}\) change over time. Half-life, represented as \(T_{1/2}\), refers to the time it takes for half of the radioactive atoms in a sample to decay. This term is different for each radioactive isotope and is a key characteristic in identifying how quickly they lose their radioactivity.
When we say that the half-life of \(^{32} \text{P}\) is 14.28 days, it implies that if you start with a certain amount of \(^{32} \text{P}\), only half of that amount will remain after 14.28 days.
This decay continues exponentially, meaning that half of the remaining material decays in the next half-life period, further reducing the quantity.
Understanding the half-life allows scientists to predict how long a substance will remain active, which is particularly useful when using radioactive tracers in experiments.
When we say that the half-life of \(^{32} \text{P}\) is 14.28 days, it implies that if you start with a certain amount of \(^{32} \text{P}\), only half of that amount will remain after 14.28 days.
This decay continues exponentially, meaning that half of the remaining material decays in the next half-life period, further reducing the quantity.
Understanding the half-life allows scientists to predict how long a substance will remain active, which is particularly useful when using radioactive tracers in experiments.
radiation counting rate
The radiation counting rate is a measure of how much radiation is being emitted from a radioactive source at any given time.
It's often measured in counts per second (cps), which tells us how frequently radiation events (like disintegrations of atoms) are being detected by a sensor.
In our given problem, the counting rate began at 3050 cps and decreased to 170 cps. This change occurs because radioactive materials decay over time, thus decreasing their emission rate. By understanding the initial and desired counting rates, and using the concept of half-life, we can determine how long it will take to reach a particular level of radioactivity.
This is crucial in experimental settings where researchers need to track the decay and ensure measurements are made under predictable conditions. The goal is to track precisely how the radioactivity decreases, providing insights into both the rate of decay and the effectiveness of the isotope as a tracer.
In our given problem, the counting rate began at 3050 cps and decreased to 170 cps. This change occurs because radioactive materials decay over time, thus decreasing their emission rate. By understanding the initial and desired counting rates, and using the concept of half-life, we can determine how long it will take to reach a particular level of radioactivity.
This is crucial in experimental settings where researchers need to track the decay and ensure measurements are made under predictable conditions. The goal is to track precisely how the radioactivity decreases, providing insights into both the rate of decay and the effectiveness of the isotope as a tracer.
tracer in biochemical reactions
Tracers are powerful tools in biochemical research, allowing scientists to study processes that would otherwise be invisible. These tracers, like \(^{32} \text{P}\), are often radioactive elements that can be incorporated into molecules within an organism.
When introduced into a system, they "trace" the physical and chemical changes, enabling researchers to follow a compound's journey through different biochemical pathways. Radioactive \(^{32} \text{P}\) is particularly useful in studies involving phosphorus cycles in plants and animals, as it mimics the natural element's behavior but allows detection through its radioactive emissions.
For instance, in the exercise example, \(^{32} \text{P}\) is introduced to a tomato plant's root system. By measuring the radiation from leaves after a set period, researchers can understand how phosphorus moves through and is utilized by the plant.
This observed behavior helps in research fields like nutrition, pharmacology, and environmental science, offering insights into everything from nutrient absorption to pollutant behavior in organisms.
When introduced into a system, they "trace" the physical and chemical changes, enabling researchers to follow a compound's journey through different biochemical pathways. Radioactive \(^{32} \text{P}\) is particularly useful in studies involving phosphorus cycles in plants and animals, as it mimics the natural element's behavior but allows detection through its radioactive emissions.
For instance, in the exercise example, \(^{32} \text{P}\) is introduced to a tomato plant's root system. By measuring the radiation from leaves after a set period, researchers can understand how phosphorus moves through and is utilized by the plant.
This observed behavior helps in research fields like nutrition, pharmacology, and environmental science, offering insights into everything from nutrient absorption to pollutant behavior in organisms.
Other exercises in this chapter
Problem 91
If the unit for atomic mass were defined so that the mass of \({ }^{1} \mathrm{H}\) were exactly \(1.000000 \mathrm{u},\) what would be the mass of (a) \({ }^{1
View solution Problem 92
High-mass radionuclides, which may be either alpha or beta emitters, belong to one of four decay chains, depending on whether their mass number \(A\) is of the
View solution Problem 96
At the end of World War II, Dutch authorities arrested Dutch artist Hans van Meegeren for treason because, during the war, he had sold a masterpiece painting to
View solution Problem 89
What is the likely mass number of a spherical nucleus with a radius of \(3.6 \mathrm{fm}\) as measured by electron-scattering methods?
View solution