Problem 69
Question
The \(p H\) of a solution ranges from 0 to \(14 .\) An acid solution has a pH less than 7. Pure water is neutral and has a pH of 7. Normal, unpolluted rain has a p \(H\) of about \(5.6 .\) The pH of a solution is given by $$ \mathrm{pH}=-\log x $$ where \(x\) represents the concentration of the hydrogen ions in the solution, in moles per liter. Use the formula to solve Exercises \(69-70\) An environmental concern involves the destructive effects of acid rain. The most acidic rainfall ever had a \(\mathrm{pH}\) of \(2.4 .\) What was the hydrogen ion concentration? Express the answer as a power of \(10,\) and then round to the nearest thousandth.
Step-by-Step Solution
Verified Answer
The concentration of hydrogen ions in the solution is approximately \(0.004\).
1Step 1: Understand the pH formula
Analyze the pH formula. The pH of a solution is given by \(-\log x\), where \(x\) is the concentration of the hydrogen ions in moles per litre.
2Step 2: Transform the formula
To find the hydrogen ion concentration (\(x\)), the formula needs to be transformed. The formula \(-\log x = pH\) can be written as \(x = 10^{-pH}\).
3Step 3: Substitute the given pH value into the formula
Substitute the value \(2.4\) (given as the pH of the most acidic rainfall) into the formula. Therefore, \(x = 10^{-2.4}\).
4Step 4: Calculate the Hydrogen ion concentration
Now, calculate the value of \(x\). To keep the answer as a power of 10, the hydrogen ion concentration is \(10^{-2.4}\).
5Step 5: Round the answer to the nearest thousandth
Calculate \(10^{-2.4}\) and round the answer to the nearest thousandth. The concentration of hydrogen ions in the solution is approximately \(0.004\).
Key Concepts
acid rainhydrogen ion concentrationlogarithms
acid rain
Acid rain is a form of precipitation that includes acidic components. It is caused by the atmosphere's reaction with pollutants, such as sulfur dioxide and nitrogen oxide. These gases are released into the sky from burning fossil fuels. When these pollutants mix with water vapor in the air, they form sulfuric and nitric acids, resulting in acid precipitation.
Acid rain can have a pH as low as 2.4, making it highly acidic and harmful to the environment.
Acid rain can have a pH as low as 2.4, making it highly acidic and harmful to the environment.
- It can damage forests by leaching essential nutrients from the soil.
- Lakes and streams can become uninhabitable for fish and other wildlife due to increased acidity.
- Monuments and buildings can erode faster due to acid's corrosive nature on certain materials.
hydrogen ion concentration
Hydrogen ion concentration is crucial in measuring the acidity or basicity of a solution. It is expressed as the number of hydrogen ions present per liter of solution. The more hydrogen ions there are, the more acidic the solution is.
For example, in the pH calculation, the concentration of hydrogen ions is represented by the variable \(x\). This relates directly to the pH value of the solution according to the formula:
Calculating this gives approximately \(0.004\), indicating that the solution is quite acidic. Understanding hydrogen ion concentration helps interpret the impacts of such conditions, including their potential harm to biological and environmental systems.
For example, in the pH calculation, the concentration of hydrogen ions is represented by the variable \(x\). This relates directly to the pH value of the solution according to the formula:
- \(\text{pH} = -\log x\)
Calculating this gives approximately \(0.004\), indicating that the solution is quite acidic. Understanding hydrogen ion concentration helps interpret the impacts of such conditions, including their potential harm to biological and environmental systems.
logarithms
Logarithms are a mathematical tool used to simplify complex calculations, especially with very large or very small numbers. In pH calculations, logarithms are vital because they enable conversion between the pH and hydrogen ion concentration in manageable terms.
- The term \("\log"\) in mathematics refers to the exponent that a base number, often 10, must be raised to produce a given number.
- The formula \(\text{pH} = -\log x\) indicates a relationship between pH and hydrogen ion concentration by using logarithms to transform the scale.
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