Problem 38 - Chemistry and Chemical Reactivity

Question

Give the symbol, including the correct charge, for each of the following ions: (a) permanganate ion (b) nitrite ion (c) dihydrogen phosphate ion (d) ammonium ion (e) phosphate ion (f) sulfite ion

Step-by-Step Solution

Answer

(a) \( \text{MnO}_4^- \), (b) \( \text{NO}_2^- \), (c) \( \text{H}_2\text{PO}_4^- \), (d) \( \text{NH}_4^+ \), (e) \( \text{PO}_4^{3-} \), (f) \( \text{SO}_3^{2-} \).

Step 1: Identify the permanganate ion

The permanganate ion is a polyatomic ion with the formula \( \text{MnO}_4^- \). It consists of one manganese atom and four oxygen atoms, and carries a -1 charge.

Step 2: Identify the nitrite ion

The nitrite ion is represented by \( \text{NO}_2^- \). It is comprised of one nitrogen atom and two oxygen atoms, and it has a -1 charge.

Step 3: Identify the dihydrogen phosphate ion

The dihydrogen phosphate ion has the formula \( \text{H}_2\text{PO}_4^- \). It contains two hydrogen atoms, one phosphorus atom, and four oxygen atoms and carries a -1 charge.

Step 4: Identify the ammonium ion

The ammonium ion is represented by \( \text{NH}_4^+ \). It consists of one nitrogen atom and four hydrogen atoms, and it carries a +1 charge.

Step 5: Identify the phosphate ion

The phosphate ion has the formula \( \text{PO}_4^{3-} \). It is comprised of one phosphorus atom and four oxygen atoms and carries a -3 charge.

Step 6: Identify the sulfite ion

The sulfite ion is represented by \( \text{SO}_3^{2-} \). It contains one sulfur atom and three oxygen atoms, and carries a -2 charge.

Key Concepts

Chemical Formulas

When we talk about chemical formulas, we are referring to a way of expressing information about the proportions of atoms that constitute a particular chemical compound or molecule. For example, in the formula \( \text{H}_2\text{O} \), which represents water, it is easy to see that there are two hydrogen atoms bonded to one oxygen atom. Similarly, polyatomic ions like the permanganate ion \( \text{MnO}_4^- \) have their own specific formulas which denote the number and type of atoms involved.

• For the permanganate ion, the chemical formula \( \text{MnO}_4^- \) consists of one manganese (Mn) atom and four oxygen (O) atoms.
• The nitrite ion, \( \text{NO}_2^- \), has one nitrogen (N) atom and two oxygen atoms.
• The phosphate ion, \( \text{PO}_4^{3-} \), comprises one phosphorus (P) atom and four oxygen atoms.
• In comparison, dihydrogen phosphate ion \( \text{H}_2\text{PO}_4^- \) includes two hydrogen (H) atoms alongside phosphorus and oxygen atoms.

Chemical formulas give us a concise way to indicate not just which atoms are present, but also in what quantity and arrangement, revealing the compound's essential properties. Understanding these formulas is crucial in inorganic chemistry as it allows us to predict interactions and reactions with other substances.

Charge of Ions

The charge of ions plays a key role in the formation of chemical compounds because it determines how ions will interact with one another. An ion can have a positive charge, meaning it is a cation, or a negative charge, meaning it is an anion. The charge arises because an ion has either gained or lost electrons, which are negatively charged particles.

• Permanganate \( \text{MnO}_4^- \) is an anion with a charge of -1.
• Nitrate ion \( \text{NO}_2^- \) also has a negative charge of -1.
• Phosphate \( \text{PO}_4^{3-} \) has a more significant negative charge, with a -3 charge.
• In contrast, the ammonium ion \( \text{NH}_4^+ \) is a cation with a single positive charge.

The interplay of positive and negative charges allows ions to form ionic bonds. The charge must be balanced for compounds to remain stable, and understanding these charges helps us write correct chemical equations, which is a foundational skill in inorganic chemistry.

Chemical Bonds

Chemical bonds are the forces that hold atoms together within a molecule or compound. There are several types of chemical bonds, including ionic, covalent, and metallic bonds. In the context of polyatomic ions, ionic and covalent bonds are most relevant.

• Ions generally come together to form ionic bonds based on their charges. A cation's positive charge is attracted to an anion's negative charge.
• In a polyatomic ion like ammonium \( \text{NH}_4^+ \), a covalent bond holds the nitrogen and hydrogen atoms together internally, while the ion as a whole can form additional ionic bonds with other ions based on charge.

Chemical bonds are also involved when polyatomic ions participate in reactions or form larger compounds. Understanding the nature of these bonds is crucial for predicting and explaining the behavior of compounds in chemical reactions, a core component of inorganic chemistry.

Inorganic Chemistry

Inorganic chemistry is a branch of chemistry concerned with the properties and behavior of inorganic compounds, which include minerals, metals, and all elements excluding organic compounds (those that contain carbon-hydrogen bonds). Understanding concepts like polyatomic ions, chemical formulas, and chemical bonding is essential in this field.

• Inorganic compounds are often formed through ionic bonds and include salts, like sodium chloride, and other compounds that do not contain carbon.
• Polyatomic ions, the subject of the exercise, are a key component of inorganic chemistry because they frequently form salts and other compounds.
• Experience with these ions helps predict the solubility, reactivity, and properties of various inorganic compounds.

Inorganic chemistry provides the foundational understanding necessary for many applications, from industrial to environmental chemistry. It requires familiarity with numerous polyatomic ions and their interactions in forming complex structures. This extends to the ability to write chemical formulas and understand resulting compound behavior.