Problem 24 - Chemistry: The Central Science in SI Units, Global Edition

Question

(a) Write an equation that expresses the first law of thermodynamics in terms of heat and work. (b) Under what conditions will the quantities \(q\) and \(w\) be negative numbers?

Step-by-Step Solution

Answer

(a) The First Law of Thermodynamics equation is: ΔU = q + w (b) The conditions for negative values of \(q\) and \(w\) are: - \(q\) is negative when heat is removed from the system. - \(w\) is negative when work is done on the system.

Step 1: (a) Formulate the First Law of Thermodynamics equation

The First Law of Thermodynamics equation is given by: ΔU = q + w where ΔU represents the change in internal energy, q represents the heat added to the system, and w represents the work done by the system.

Step 2: (b) Identify conditions for negative q and w values

Let's analyze the conditions that make the heat (\(q\)) and work (\(w\)) quantities negative. 1. Negative heat (q < 0): Heat is considered negative when it's being removed from the system. This is because heat leaving the system causes the internal energy of the system to decrease. 2. Negative work (w < 0): Work is considered negative when the work is done on the system. This is because when work is performed on the system, the internal energy of the system increases as a consequence of an external force acting on it. So, - \(q\) will be negative when heat is removed from the system. - \(w\) will be negative when work is done on the system.

Key Concepts

Understanding Internal Energy

When we talk about internal energy in thermodynamics, we're focusing on the energy contained within a system. This energy is due to the microscopic motions of atoms and molecules. In simpler terms, internal energy is like the internal bank account of energy that a system has.
It includes kinetic and potential energy at the molecular level.
Internal energy can change due to two main factors: heat and work. When heat is added to a system, the internal energy increases. Likewise, when heat is removed, it decreases.
Similarly, when work is done by the system, the internal energy decreases, and when work is done on the system, the internal energy increases. These changes are captured by the First Law of Thermodynamics, which shows how a system exchanges energy with its surroundings through heat and work.
This is crucial because it helps us understand energy transformations in scientific and engineering problems involving gases, engines, and even biological systems.

Heat Transfer Basics

Heat transfer is a key concept in thermodynamics, and it describes the movement of heat energy from one place to another. Heat always flows from a hotter object to a cooler one, as per the Second Law of Thermodynamics.
There are three main types of heat transfer:

• Conduction: Transfer of heat through direct contact of particles.
• Convection: Transfer of heat by the movement of fluids or gases.
• Radiation: Transfer of heat through electromagnetic waves, like the warmth you feel from the sun.

In the context of the First Law of Thermodynamics, the symbol \(q\) represents heat. If \(q\) is positive, it indicates heat added to the system. Conversely, if \(q\) is negative, heat is leaving or being removed from the system.
This movement of heat affects the internal energy and, therefore, the state of the system.

Exploring Work Done

Work done in thermodynamics is a measure of energy transfer which occurs when a force moves an object. It's like the energy you expend to push a heavy box across the floor. In terms of a system, it's about how energy is transferred through moving boundaries or changes in volume. Work can be either positive or negative. According to the First Law of Thermodynamics, when the system does work, we often consider it positive \((w > 0)\), as energy is leaving the system.
However, when work is done on the system, it's negative \((w < 0)\), meaning the system is gaining energy due to external influence.
Understanding these basics of work helps explain phenomena in engines where gases expand and do work, or in refrigeration cycles, where work is done on a system to remove heat. Work done alongside heat transfer ties back into changing the internal energy of a system, completing our picture of energy conservation and transfer as described by the First Law of Thermodynamics.