Problem 14
Question
(a) Are you more likely to see the density of a gas reported in \(\mathrm{g} / \mathrm{mL}, \mathrm{g} / \mathrm{L},\) or \(\mathrm{kg} / \mathrm{cm}^{3} ?(\mathbf{b})\) Which units are appropriate for expressing atmospheric pressures, \(\mathrm{N}, \mathrm{Pa}, \mathrm{atm}, \mathrm{kg} / \mathrm{m}^{2} ?\) (c) Which is most likely to be a gas at room temperature and ordinary atmospheric pressure, \(\mathrm{F}_{2}, \mathrm{Br}_{2}, \mathrm{~K}_{2} \mathrm{O}\)
Step-by-Step Solution
Verified Answer
(a) \(\text{g/L}\). (b) \(\text{Pa}\) or \(\text{atm}\). (c) \(\text{F}_2\).
1Step 1: Understanding Gas Density Units
Gases have densities much lower than liquids and solids, usually expressed in larger volumes. In chemistry, the density of a gas is commonly reported in \(\text{g/L}\) because gases are typically measured in liters at standard conditions. \(\text{g/mL}\) is more common for liquids, and \(\text{kg/cm}^3\) is not practical for gases because it involves very small values.
2Step 2: Units for Atmospheric Pressure
Atmospheric pressure is commonly expressed in \(\text{atm}\) and \(\text{Pa}\). The Pascal \((\text{Pa})\) is the SI unit for pressure, while \(\text{atm}\) is useful for practical, everyday measures. \(\text{N}\) (newtons) is a force unit, not a pressure unit, and \(\text{kg/m}^2\) is incorrect because it doesn't have time in the units to constitute pressure.
3Step 3: Identifying Gaseous Substance
Under normal conditions (room temperature and atmospheric pressure), \(\text{F}_2\) (Fluorine) is a gas, \(\text{Br}_2\) (Bromine) is a liquid, and \(\text{K}_2\text{O}\) (Potassium Oxide) is a solid. Therefore, \(\text{F}_2\) is the choice most likely to be a gas under these conditions.
Key Concepts
Atmospheric Pressure UnitsGaseous State at Room TemperatureSI Units for Pressure
Atmospheric Pressure Units
Atmospheric pressure is the pressure within the earth's atmosphere. It's important to understand the units used to express atmospheric pressure in order to properly interpret scientific data.
- The most common units for expressing atmospheric pressure are atmospheric pressure (atm) and Pascal (Pa).
- Pascals are the SI units for pressure, making it essential for scientific applications. This is because it uses meters, kilograms, and seconds—the fundamental SI units.
- Atmosphere (atm) is often used in everyday contexts and practical applications, measuring pressure in terms we can easily observe at sea level.
- While newtons (N) and kilograms per square meter ( kg/m^2 ) might seem relevant, they lack the necessary time component that pressure units require. This is why they're not typically used to express atmospheric pressure.
Gaseous State at Room Temperature
Certain substances are more likely to be in a gaseous state at room temperature and atmospheric pressure. This is important for understanding and predicting how substances behave in different environments.
- F_2 , or Fluorine, is a diatomic gas under normal conditions, making it a frequent example of a gaseous element at room temperature.
- Br_2 (Bromine), on the other hand, is a liquid, highlighting how similar elements can exist in different states due to variations in molecular interactions and atomic weight.
- K_2O (Potassium Oxide) is a solid, demonstrating how compounds, especially ionic ones, tend to be solids due to strong ionic bonds that require higher temperatures to break.
SI Units for Pressure
The SI unit for pressure is the Pascal (Pa), which is vital for scientific work. Understanding SI units ensures precision and universal understanding in measurements. Here are some important points:
- The Pascal is defined as one newton per square meter (1 Pa = 1 N/m^2), reflecting how pressure is calculated as force per unit area.
- SI units enable international consistency, especially in scientific research, as they are universally accepted and standardized.
- Pascal units can also be converted to kilopascals (kPa) for larger pressures, which is useful in scientific and engineering contexts.
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