Problem 100 - Chemistry The Central Science

Question

An aluminum can of a soft drink is placed in a freezer. Later, you find that the can is split open and its contents have frozen. Work was done on the can in splitting it open. Where did the energy for this work come from?

Step-by-Step Solution

Answer

The energy for the work done on the aluminum can, causing it to split open, comes from the heat released during the freezing process of the soft drink. As the liquid inside the can loses heat energy to the surroundings (the freezer) and becomes a solid, the energy released is used to perform mechanical work on the can, causing it to deform and eventually split open.

Step 1: Understand the freezing process

First, let's understand what happens when the soft drink freezes. When the can is placed in the freezer, the temperature of the liquid inside the can decreases. As the temperature decreases, the liquid molecules slow down and eventually align themselves in an organized pattern. This process causes the liquid to change its phase into a solid (in this case, ice). When water freezes, it expands and requires more volume.

Step 2: Identify what causes the can to split

When the liquid inside the can freezes and expands, it puts a force on the walls of the aluminum can. The walls of the can need to expand to accommodate the increased volume of the solid. If the force exerted by the expanding ice is greater than the can's material strength, the can will deform and eventually split open.

Step 3: Identify the energy conversion

Now, we know that there is a force applied to the walls of the can. This force results in mechanical work being done on the can, causing it to split open. The energy for this work must come from somewhere. During the freezing process, energy is released in the form of heat as the liquid inside the can loses energy to the surroundings (the freezer). This is because the molecules in the liquid slow down and arrange themselves into a solid state, which generally has lower energy than a liquid state.

Step 4: Identify the source of energy

We can now conclude that the energy for the work done on the can, which caused it to split open, comes from the heat released during the freezing process of the soft drink. As the soft drink loses heat energy (exothermic process) and becomes a solid, the energy that is released is used to perform mechanical work on the aluminum can, causing it to deform and eventually split open.