24.134 CP - Chemistry: Molecular Nature Of Matter And Change

Question

Uranium-233 decays to thorium-229 by decay, but the emissions have different energies and products: 83% emit an  particle with energy of 4.816 MeV and give 229Th in its ground state; 15% emit an  particle of  4.773 MeV and give ²²⁹Th in excited state I; and2%  emit a lower energy  particle and give 229Th in the higher excited state II. Excited state II emits a ray of 0.060 MeV to reach excited state I. 

(a) Find the $\gamma$-ray energy and wavelength that would convert excited state I to the ground state. 

(b) Find the energy of the particle that would convert  ²³³U to excited state II.

 

Step-by-Step Solution

Answer

(a) The $\lambda$-ray energy and wavelength are: E = 0.043 MeV and $\lambda =2.8836\times {10}^{-11} m$.

(b) The energy of the particle =4.173 MeV .

Step 1: Definition of Nuclear Reactions

The distance between “two crests” is the wavelength of a wave. 

 

Representation of wave

In mathematics, the Greek symbol lambda () is used to indicate wavelength.

Step 2: Find the γ -ray energy and wavelength

A. Determine the $\gamma$-ray energy and wavelength required to convert the excited state. 

 

We need to use this formula:

….. (i)

 

• $\gamma$= Wavelength
• h = Planck’s constant
• c = Speed of light
• E = Energy

 

The binding energies are generally represented in millions of electron volts, or mega-electron volts (MeV), for the derivation:

$$\begin{gathered} 1MeV={10}^{6}eV \\ =1.602x{10}^{-13} J \end{gathered}$$

$$\begin{gathered} Energy(\gamma -ray)=(4.816-4.773)MeV \\ =0.043MeV \end{gathered}$$

The known values are substituted.

$\lambda =\frac{\left(6.626x{10}^{-34} J.s\right)\left(\left(2.99792x{10}^8\frac{m}{s}\right.\right)}{0.043MeV}\times \left(\frac{1MeV}{1.602\times {10}^{-13}}\right)$

 

Therefore, the gamma-ray energy is 0.043 MeV and wavelength $\lambda =2.8836\times {10}^{-11} m$.

Step 3: Find the energy of the particle

B. The energy of a particle that would convert ²³³U to excited state II,

 $$\begin{gathered} Energy=4.816MeV-\left(0.043MeV-0.060MeV\right) \\ =4.713MeV \end{gathered}$$

Therefore, the energy of the particle =4.173 MeV.